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FM2021-0003ADDITIONAL SITES CHRONOLOGY CONTACTS NAME TYPE NAME ADDRESS1 CITY STATE ZIP PHONE FAX EMAIL APPLICANT Marcos Perales 52115 Avenida Bermudas La Quinta CA 92253 (760)574-3530 marcos.perales@gmail. com CONTRACTOR Marcos Perales 52115 Avenida Bermudas La Quinta CA 92253 (760)574-3530 marcos.perales@gmail. com OWNER LQ INV 17165 NEWHOPE ST FOUNTAIN VALLEY CA 92253 (760)574-3530 CONDITIONS Description: DISCOUNT POOL & SPA SUPPLY - HAZ MAT OPS PERMIT Type: FIRE MISCELLANEOUS (WEB)Subtype: Status: FINALED Applied: 9/27/2021 EPRS Parcel No: 770020017 Site Address: 50855 WASHINGTON ST STE 2B LA QUINTA,CA 92253 Approved: 9/29/2021 KHET Subdivision: PM 27984 Block: Lot: 3 Issued: Lot Sq Ft: 0 Building Sq Ft: 0 Zoning: Finaled: 9/29/2021 KHET Valuation: $0.00 Occupancy Type: Construction Type: Expired: No. Buildings: 0 No. Stories: 0 No. Unites: 0 Details: Discount Pool and Spa supply (Unit 2b) FINANCIAL INFORMATION Printed: Thursday, February 23, 2023 4:47:37 PM 1 of 3 Permit Details City of La Quinta PERMIT NUMBER FM2021-0003 ATTACHMENTS Attachment Type CREATED OWNER DESCRIPTION PATHNAME SUBDIR ETRAKIT ENABLED DOC 9/27/2021 Etrakit Public Registration ps-super-algae- destroyer-sds.pdf 1 DOC 9/27/2021 Etrakit Public Registration Hasachlor-SDS.pdf 1 DOC 9/27/2021 Etrakit Public Registration Muriatic Acid SDS.pdf 1 DOC 9/27/2021 Etrakit Public Registration super-shockwave- sds.pdf 1 BOND INFORMATION INSPECTIONS SEQID INSPECTION TYPE INSPECTOR SCHEDULED DATE COMPLETED DATE RESULT REMARKS NOTES FIRE FINAL**KHET 9/29/2021 9/29/2021 APPROVED see attachment for issued Fire Operational Permit. REVIEWS REVIEW TYPE REVIEWER SENT DATE DUE DATE RETURNED DATE STATUS REMARKS NOTES 1ST FIRE - ETRAKIT (1 WK) KOHL HETRICK 9/27/2021 9/28/2021 9/29/2021 APPROVED SEE ATTACHMENTS REVIEW TIME FRAME CHANGED TO 1 DAY PARENT PROJECTS DESCRIPTION ACCOUNT QTY AMOUNT PAID PAID DATE RECEIPT #CHECK #METHOD PAID BY CLTD BY FIRE STAFF - PER HOUR 101-0000-42420 1 $161.00 $161.00 9/29/21 WEB9447 632705039 16 CREDIT Marcos Perales EPRS Total Paid for FIRE FEES: $161.00 $161.00 TOTALS:$161.00 $161.00 Printed: Thursday, February 23, 2023 4:47:37 PM 2 of 3 Permit Details City of La Quinta PERMIT NUMBER FM2021-0003 ATTACHMENTS Attachment Type CREATED OWNER DESCRIPTION PATHNAME SUBDIR ETRAKIT ENABLED DOC 9/27/2021 Etrakit Public Registration ps-chlor-conc-sds.pdf 1 DOC 9/29/2021 KOHL HETRICK FM2021-0003 - HAZMAT OPS PERMIT.pdf FM2021-0003 - HAZMAT OPS PERMIT.pdf 1 DOC 10/6/2021 KOHL HETRICK 8-10-2021 - Email Listing Stock Order.pdf 8-10-2021 - Email Listing Stock Order.pdf 1 DOC 10/6/2021 KOHL HETRICK FM2021-0003 - HAZMAT OPS PERMIT.pdf FM2021-0003 - HAZMAT OPS PERMIT_1.pdf 1 DOC 10/6/2021 KOHL HETRICK FM2021-0003 - HAZ MAT INV STATEMENT (CONSOLIDATED).pdf FM2021-0003 - HAZ MAT INV STATEMENT (CONSOLIDATED).pdf 1 PHOTO 9/27/2021 Etrakit Public Registration PXL_20210927_1333205 04.jpg 1 PHOTO 9/27/2021 Etrakit Public Registration PXL_20210927_1333411 69.jpg 1 PHOTO 9/27/2021 Etrakit Public Registration PXL_20210927_1333094 35.jpg 1 PHOTO 9/27/2021 Etrakit Public Registration PXL_20210927_1331580 26.jpg 1 Printed: Thursday, February 23, 2023 4:47:37 PM 3 of 3 Permit Details City of La Quinta PERMIT NUMBER FM2021-0003 SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 1 of 14 FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: FOR ALL SDS QUESTIONS & REQUESTS, CALL: 1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347) PRODUCT NAME: Super Shockwave Shock Treatment for Swimming Pools EPA Registration Number: 1258-1239-42177 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Arch Chemicals, Inc. 1200 Bluegrass Lakes Parkway Alpharetta, GA 30004 REVISION DATE: 06/03/2015 SUPERCEDES: 05/27/2015 MSDS Number: 000000023371 SYNONYMS: None CHEMICAL FAMILY: Hypochlorite DESCRIPTION / USE Sanitizer and OxidizerWater treatment chemical FORMULA: NOT APPLICABLE/MIXTURE SECTION 2. HAZARDS IDENTIFICATION GHS Classification Oxidizing solids : Category 2 Acute toxicity (Oral) : Category 4 Skin corrosion : Category 1B Serious eye damage : Category 1 Acute toxicity (Inhalation) : Category 3 Specific target organ toxicity - single exposure : Category 3 GHS Label element SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 2 of 14 Hazard pictograms : Signal word : Danger Hazard statements : H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. Precautionary statements : Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P220 Keep/Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. P260 Do not breathe vapours. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/ physician. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide to extinguish. Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal: P501 Dispose of contents/container in accordance with local regulation. Other hazards None known. SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 3 of 14 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS OR CHEMICAL NAME CAS # % RANGE CALCIUM HYPOCHLORITE 7778-54-3 60 - 80 SODIUM CHLORIDE 7647-14-5 10 - 20 CALCIUM CHLORATE 10137-74-3 0 - 5 CALCIUM CHLORIDE 10043-52-4 0 - 5 CALCIUM HYDROXIDE 1305-62-0 0 - 4 CALCIUM CARBONATE 471-34-1 0 - 5 Water 7732-18-5 7 - 16 SECTION 4. FIRST AID MEASURES General Advice: Call a poison control center or doctor for treatment advice. For 24-hour emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. Inhalation: IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Skin Contact: IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Eye Contact: IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Ingestion: IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Notes to Physician: Probable mucosal damage may contraindicate the use of gastric lavage. SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 4 of 14 SECTION 5. FIREFIGHTING MEASURES Flammability Summary (OSHA): This product is chemically reactive with many substances. Any contamination of the product with other substances by spill or otherwise may result in a chemical reaction and fire., This product is a strong oxidizer which is capable of intensifying a fire once started., Product is not known to be flammable, combustible or pyrophoric. Flammable Properties Flash Point: Not applicable Autoignition Temperature: Not applicable Extinguishing Media: Water only. Do not use dry extinguishers containing ammonium compounds. Fire Fighting Instructions: Use water to cool containers exposed to fire. See Section 6 for protective equipment for fire fighting. Upper Flammable / Explosive Limit, % in air: Not applicable Lower Flammable / Explosive Limit, % in air: Not applicable SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Protection for Emergency Situations: Response to a large quantity spill (100 pounds or greater) or when dusting or decomposition gas exposure could occur requires the use of a positive pressure full face supplied air repirator or self contained breathing apparatus (SCBA), chemical resistant gloves, coveralls and boots. In case of fire, this personal protective equipment should be used in addition to normal fire fighter equipment. Spill Mitigation Procedures Air Release: Vapors may be suppressed by the use of water fog. All water utilized to assist in fume suppression, decontamination or fire suppression may be contaminated and must be contained before disposal and/or treatment. Water Release: This product is heavier than water. This material is soluble in water. Monitor all exit water for available chlorine and pH. Advise local authorities of any contaminated water release. SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 5 of 14 Land Release: Contact 1-800-654-6911 immediately. DANGER: All spills of this product should be treated as contaminated. Contaminated product may initiate a chemical reaction that may spontaneously ignite any combustible material present, resulting in a fire of great intensity. In case of a spill, separate all spilled product from packaging, debris and other material. Using a clean broom or shovel, place all spilled product into plastic bags, and place those bags into a clean, dry disposal container, properly marked and labeled. Disposal containers made of plastic or metal are recommended. Do not seal disposal containers tightly. Immediately remove all product in disposal containers to an isolated area outdoors. Place all damaged packaging material in a disposal container of water to assure decontamination (i.e. removal of all product) before disposal. Place all undamaged packaging in a clean, dry container properly marked and labeled. Call for disposal procedures. Additional Spill Information : Hazardous concentrations in air may be found in local spill area and immediately downwind. Remove all sources of ignition. Stop source of spill as soon as possible and notify appropriate personnel. Dispose of spill residues per guidelines under Section 13, Disposal Consideration. This material may be neutralized for disposal; you are requested to contact Arch Chemicals at 1-800-654-6911 before beginning any such procedure. FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC: 1-800-424-9300 REPORTABLE QUANTITY: 10 lbs. (as calcium hypochlorite) per 40 CFR 302.4. SECTION 7. HANDLING AND STORAGE Handling: Avoid inhalation of dust and fumes. Do not take internally. Avoid contact with skin, eyes and clothing. Upon contact with skin or eyes, wash off with water. Remove contaminated clothing and wash before reuse. Storage: Keep product tightly sealed in original containers. Store product in a cool, dry, well-ventilated area. Store away from combustible or flammable products. Keep product packaging clean and free of all contamination, including, e.g. other pool treatment products, acids, organic materials, nitrogen-containing compounds, dry powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. Shelf Life Limitations: Do not store product where the average daily temperature exceeds 95° F. Storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. Shelf life (that is, the period of time before the product goes below stated label strength) is determined by storage time and temperatures. Store in a cool, dry and well ventilated area. Prolonged storage at elevated temperatures will significantly shorten the shelf life. Storage in a climate controlled storage area or building is recommended in those areas where extremes of high temperature occur. SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 6 of 14 Incompatible Materials for Storage: Do not allow product to come in contact with other materials, including e.g. other pool treatment products, acids, organic materials, nitrogen-containing compounds, dry powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. A chemical reaction with such substances can cause a fire of great intensity. Do Not Store At temperatures Above: Average daily temperature of 35° C / 95° F. Storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep airborne exposures below the TLV, PEL or other recommended exposure limit. Protective Equipment for Routine Use of Product Respiratory Protection : Wear a NIOSH approved respirator if levels above the exposure limits are possible. Respirator Type : A NIOSH approved full-face air purifying respirator equipped with combination chlorine/P100 cartridges. Air purifying respirators should not be used in oxygen deficient or IDLH atmospheres or if exposure concentrations exceed ten (10) times the published limit. Skin Protection : Wear impervious gloves to avoid skin contact. A full impervious suit is recommended if exposure is possible to a large portion of the body. A safety shower should be provided in the immediate work area. Eye Protection: Use chemical goggles. Emergency eyewash should be provided in the immediate work area. Protective Clothing Type: Neoprene, Nitrile, Natural rubber (This includes: gloves, boots, apron, protective suit) Components with workplace control parameters Components (CAS-No.) Value Control parameters Basis (Update) CALCIUM HYPOCHLORITE (7778-54-3) TWA 1 mg/m3 ARCH OEL* CALCIUM HYPOCHLORITE (7778-54-3) Conc 37 - 48 mg/m3 NIOSH/GUIDE IDLH CALCIUM HYDROXIDE (1305-62-0) TWA 5 mg/m3 ACGIH (02 2014) ARCH OEL: Arch Recommended Occupational Expos ure Guideline. SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 7 of 14 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: solid Form Free flowing, granular Color: white Odor: Chlorine-like Molecular Weight: (Active ingredient)143.00 g/mol pH : 10.4 - 10.8 (1% solution in neutral, distilled water) (@ 25 Deg. C) Boiling Point: Not applicable Melting point/freezing point Not applicable Density: 0.8g/cc Vapor Pressure: (@ 25 Deg. C) Not applicable Vapor Density: Not applicable Viscosity: Not applicable Fat Solubility: No data Solubility in Water: 18 % (@ 25 Deg. C) Product also contains calcium hydroxide and calcium carbonate which will leave a residue. Partition coefficient n- octanol/water: No data Evaporation Rate: Not applicable Oxidizing: Oxidizer Volatiles, % by vol.: Not applicable VOC Content This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450. HAP Content Not applicable SECTION 10. STABILITY AND REACTIVITY Stability and Reactivity Summary: Product is not sensitive to mechanical shock or impact. Product is not sensitive to electrical static discharge. Product will not undergo hazardous polymerization. Product is an NFPA Class 3 oxidizer which can cause a severe increase in fire intensity. Not pyrophoric. Not an organic peroxide. If subjected to excessive temperatures, the product may undergo rapid decomposition, evolution of chlorine gas, and heat sufficient to ignite combustible substances. If product is exposed to small amounts of water, it can react violently to produce heat and toxic gases and spatter. Use copious amounts of water for fires involving this product. Conditions to Avoid: Do not store next to heat source, in direct sunlight, or elevated storage temperature. Do not store where the daily average temperature exceeds 95 °F. Prevent ingress of humidity and moisture into container or package. Always close the lid. Chemical Incompatibility: This product is chemically reactive with many substances, including, e.g., other pool treatment products, acids, organics, nitrogen-containing compounds, dry powder fire extinguishers SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 8 of 14 (containing mono-ammonium phosphate), oxidizers, corrosive ,flammable or combustible materials. Do not allow product to contact any foreign matter, including other water treatment products. Contamination or improper use may cause a fire of great intensity, explosion or the release of toxic gases. If product is exposed to small amounts of water, it can react violently to produce heat and toxic gases and spatter. Hazardous Decomposition Products: Chlorine Decomposition Temperature: 170 - 180 °C - , 338 - 356 °F- SECTION 11. TOXICOLOGICAL INFORMATION Component Animal Toxicology Oral LD50 value: CALCIUM HYPOCHLORITE LD50 (65% calcium hypochlorite) 850 mg/kg Rat SODIUM CHLORIDE LD50 = 3,000 mg/kg Rat CALCIUM CHLORIDE LD50 = 1,000 mg/kg Rat CALCIUM HYDROXIDE LD50 = 7,340 mg/kg Rat Component Animal Toxicology Dermal LD50 value: CALCIUM HYPOCHLORITE LD50 (65% calcium hypochlorite) > 2,000 mg/kg Rabbit SODIUM CHLORIDE LD50 > 10,000 mg/kg Rabbit CALCIUM CHLORIDE LD50 = 2,630 mg/kg Rat CALCIUM HYDROXIDE No data Component Animal Toxicology Inhalation LC50 value: CALCIUM HYPOCHLORITE Inhalation LC50 1 h (65% calcium hypochlorite), (Nose Only) = 2.04 mg/l Rat Inhalation LC50 4 h (65% calcium hypochlorite), (Nose Only) = 0.51 mg/l Rat SODIUM CHLORIDE Inhalation LC50 1 h > 42 mg/l Rat CALCIUM CHLORIDE No data CALCIUM HYDROXIDE No data Product Animal Toxicity Oral LD50 value: LD50 Approximately 800 mg/kg Rat Dermal LD50 value: LD50 > 2,000 mg/kg Rabbit SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 9 of 14 Inhalation LC50 value: Inhalation LC50 1.00 h (Nose Only) > 2.04 mg/l Rat Inhalation LC50 4 h (Nose Only) > 0.51 mg/l Rat Inhalation LC50 1 h (Nose Only) > 2.04 mg/l Rat Inhalation LC50 4 h (Nose Only) > 0.51 mg/l Rat Skin Irritation: DRY MATERIAL CAUSES MODERATE SKIN IRRITATION., WET MATERIAL CAUSES SKIN BURNS. Eye Irritation: Corrosive to eyes. Skin Sensitization: This material is not known or reported to be a skin or respiratory sensitizer. Acute Toxicity: This product is corrosive to all tissues contacted and upon inhalation, may cause irritation to mucous membranes and respiratory tract.The dry material is irritating to the skin. However when wet, it will produce burns to the skin. Subchronic / Chronic Toxicity: There are no known or reported effects from repeated exposure except those secondary to burns. Reproductive and Developmental Toxicity: Calcium hypochlorite has been tested for teratogenicity in laboratory animals. Results of this study have shown that calcium hypochlorite is not a teratogen. CALCIUM CHLORIDE Not known or reported to cause reproductive or developmental toxicity. Mutagenicity: Calcium hypochlorite has been tested in the Dominant lethal assay in male mice, and it did not induce a dominant lethal response. Calcium hypochlorite has been reported to produce mutagenic activity in two in vitro assays . It has, however, been shown to lack the capability to produce mutations in animals based on results from the micronucleus assay. In vitro assays frequently are inappropriate to judge the mutagenic potential of bactericidal chemicals due to a high degree of cellular toxicity. The concentration which produces mutations in these in vitro assays is significantly greater than the concentrations used for disinfection. Based on high cellular toxicity in in vitro assays and the lack of mutagenicity in animals, the risk of genetic damage to humans is judged not significant. CALCIUM CHLORIDE This product was determined to be non-mutagenic in the Ames assay. It was also shown to be non- clastogenic in the chromosomal aberration test. Carcinogenicity: This product is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP or EPA. One hundred mice were exposed dermally 3 times a week for 18 months to a solution of calcium hypochlorite. Histopathological examination failed to show an increased incidence of tumors. IARC (International Agency for Research on Cancer) reviewed studies conducted with several hypochlorite salts. IARC has classified hypochlorite salts as having inadequate evidence for carcinogenicity to humans and animals. IARC therefore considers hypochlorite salts to be not classifiable as to their carcinogenicity to humans (Group 3 Substance). CALCIUM CHLORIDE This chemical is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP, or EPA. SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 10 of 14 SECTION 12. ECOLOGICAL INFORMATION Overview: Highly toxic to fish and other aquatic organisms. Ecological Toxicity Values for: CALCIUM HYPOCHLORITE Bluegill - (nominal, static). 96 h LC50 0.088 mg/l Rainbow trout (Salmo gairdneri), - (nominal, static). 96 h LC50 0.16 mg/l Daphnia magna, - (nominal, static). 48 h LC50 0.11 mg/l Bobwhite quail - Dietary LC50 > 5,000 ppm Mallard ducklings - Dietary LC50 > 5,000 ppm Bobwhite quail - Oral LD50 3,474 mg/kg Ecological Toxicity Values for: CALCIUM CHLORIDE Bluegill - (nominal, static). 96 h LC50 = 10,650 mg/l Mosquito fish - (nominal, static). 96 h LC50 = 13,400 mg/l Pimephales promelas (fathead minnow) - (nominal, static). 96 h LC50 = 4,630 mg/l Daphnia magna, - (nominal, static). 48 h LC50= 2,770 mg/l Ceriodaphnia dubia - (nominal, static). 48 h LC50= 1,830 mg/l Nitzschia linearis (diatom) - (nominal, static). 5 day LC50 = 3,130 mg/l SECTION 13. DISPOSAL CONSIDERATIONS CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THE MATERIAL. THE USER OF THE MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL REL EVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. Waste Disposal Summary : If this product becomes a waste, it meets the criteria of a hazardous waste as defined under 40 CFR 261 and would have the following EPA hazardous waste number: D001.If this product becomes a waste, it will be a hazardous waste which is subject to the Land Disposal restrictions under 40 CFR 268 and must be managed accordingly. Disposal Methods : As a hazardous solid waste it should be disposed of in accordance with local, state and federal regulations. Potential US EPA Waste Codes : D001 SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 11 of 14 SECTION 14. TRANSPORT INFORMATION DOT UN number : 2880 Description of the goods : Calcium hypochlorite, hydrated mixtures Class : 5.1 Packing group : II Labels : 5.1 Emergency Response Guidebook Number : 140 TDG UN number : 2880 Description of the goods : CALCIUM HYPOCHLORITE, HYDRATED MIXTURE Class : 5.1 Packing group : II Labels : 5.1 IATA UN number : 2880 Description of the goods : Calcium hypochlorite, hydrated mixture Class : 5.1 Packing group : II Labels : 5.1 Packing instruction (cargo aircraft) : 562 Packing instruction (passenger aircraft) : 558 Packing instruction (passenger aircraft) : Y544 IMDG-CODE UN number : 2880 Description of the goods : CALCIUM HYPOCHLORITE, HYDRATED MIXTURE Class : 5.1 Packing group : II Labels : 5.1 EmS Number 1 : F-H EmS Number 2 : S-Q Marine pollutant : yes SECTION 15. REGULATORY INFORMATION SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 12 of 14 This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. Signal word : DANGER! Hazard statements : Causes substantial but temporary eye injury. Corrosive. Causes skin burns. Corrosive. Causes irreversible eye damage. This pesticide is toxic to fish. EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Calcium hypochlorite 7778-54-3 10 SARA 302 No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Sectio n 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116.4A: Calcium hypochlorite 7778-54-3 The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 13 of 14 Calcium hypochlorite 7778-54-3 This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 US State Regulations Massachusetts Right To Know Calcium hypochlorite 7778-54-3 Calcium carbonate 471-34-1 Calcium chlorate 10137-74-3 Calcium dihydroxide 1305-62-0 Pennsylvania Right To Know Calcium hypochlorite 7778-54-3 Sodium chloride 7647-14-5 Calcium carbonate 471-34-1 Calcium chlorate 10137-74-3 Calcium chloride 10043-52-4 Calcium dihydroxide 1305-62-0 New Jersey Right To Know Calcium hypochlorite 7778-54-3 Sodium chloride 7647-14-5 Calcium carbonate 471-34-1 Calcium chlorate 10137-74-3 Calcium chloride 10043-52-4 Calcium dihydroxide 1305-62-0 California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA : This is an EPA registered pesticide. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION SECTIONS REVISED: 1 Major References : Available upon request. SAFETY DATA SHEET Super Shockwave Shock Treatment for Swimming Pools REVISION DATE : 06/03/2015 Page 14 of 14 THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. ARCH CHEMICALS BELIEVES THIS INFORMATION TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION BUT, MAKES NO WARRANTY THAT IT IS. ADDITIONALLY, IF THIS MSDS IS MORE THAN THREE YEARS OLD, YOU SHOULD CONTACT ARCH CHEMICALS MSDS CONTROL AT THE PHONE NUMBER ON THE FRONT PAGE TO MAKE CERTAIN THAT THIS DOCUMENT IS CURRENT. . HASACHLOR Safety Data Sheet (SDS No. 102) Revision Date: 01/01/2016 (Supersedes previous revisions) Page 1 of 10 HASACHLOR Safety Data Sheet 12.5% Sodium Hypochlorite Emergency 24 Hour Telephone: CHEMTREC 800.424.9300 Corporate Headquarters: Hasa Inc. P.O. Box 802736 Santa Clarita, CA 91355 Telephone 661.259.5848 Fax 661.259.1538 SECTION 1: IDENTIFICATION 1.1 Product Identification: 1.1.1 Product Name: HASACHLOR 1.1.2 CAS # (Chemical Abstracts Service): 7681-52-9 1.1.3 RTECS (Registry of Toxic Effects of Chemical Substances): NH3486300 1.1.4 EINECS (European Inventory of Existing Commercial Substances): 231-668-3 1.1.5 EC Number: 231-668-3 1.1.6 Synonym: Bleach, Hypo, Hypochlorite, Liquid Chlorine Solution 1.1.7 Chemical Name: Sodium Hypochlorite 1.1.8 Chemical Formula: NaOCl 1.2 Recommended Uses: Sanitizer of swimming pool and spa water. 1.3 Company Identification: Hasa Inc. P. O. Box 802736 Santa Clarita, CA 91355 1.4 Emergency Telephone Number: CHEMTREC 1-800-424-9300 (24 hour Emergency Telephone) 1.5 Non-Emergency Assistance: 661-259-5848 (8 AM – 5 PM PST / PDT) HASACHLOR Safety Data Sheet (SDS No. 102) Revision Date: 01/01/2016 (Supersedes previous revisions) Page 2 of 10 SECTION 2: HAZARD(S) IDENTIFICATION HEALTH HAZARD Skin corrosion / irritation: Category 1 Serious Eye damage / Eye Irritation Category 1 Specific target organ toxicity, single exposure Category 3 (respiratory tract irritation) ENVIRONMENTAL HAZARD Hazardous to the aquatic environment, acute hazard Category 1 PHYSICAL HAZARD Corrosive to metals. Category 1 SYMBOLS SIGNAL WORD DANGER HAZARD STATEMENT May be corrosive to metals. Causes severe skin burns and eye damage. May cause respiratory irritation. Very toxic to aquatic life. PRECAUTIONARY STATEMENT Prevention Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe mist or vapor. Use only outdoors or in a well- ventilated area. Wash thoroughly after handling. Keep only in original container. Avoid release to the environment. Response If swallowed: Rinse mouth. Do NOT induce vomiting. If inhaled: Remove person to fresh air and keep comfortable for breathing. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Collect spillage. Storage and Disposal Store in a well-ventilated place. Keep container tightly closed. Store locked up. Store in corrosive resistant container. Dispose of container/contents in accordance with local, regional, national, international regulations as specified. SECTION 3: COMPOSITION INFORMATION ON INGREDIENTS Ingredient Synonyms CAS No. Weight % 3.1 Sodium Hypochlorite Bleach 7681-52-9 12.5% 3.2 Sodium Hydroxide Caustic Soda 1310-73-2 0.2% HASACHLOR Safety Data Sheet (SDS No. 102) Revision Date: 01/01/2016 (Supersedes previous revisions) Page 3 of 10 SECTION 4: FIRST AID MEASURES 4.1 IF IN EYES • Hold eye open and rinse slowly and gently with water for 15-20 minutes. • Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. • Call a poison control center or doctor for treatment advice. 4.2 IF ON SKIN OR CLOTHING • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15-20 minutes. • Call a poison control center or doctor for treatment advice. 4.3 IF INHALED • Move person to fresh air. • If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. • Call a poison control center or doctor for further treatment advice. 4.4 IF SWALLOWED • Call a poison control center or doctor immediately for treatment advice. • Have person sip a glass of water if able to swallow. • Do not induce vomiting unless told to do so by a poison control center or doctor. • Do not give anything by mouth to an unconscious person. HOT LINE NUMBER Have the product container or label with you when calling a poison control center or doctor, or going for treatment. You may also contact 1-800-424-9300 for emergency medical treatment information. NOTE TO PHYSICIAN Probable mucosal damage may contraindicate the use of gastric lavage. SECTION 5: FIRE FIGHTING MEASURES 5.1 Flash Point: Not applicable. 5.2 Flammability: Nonflammable and noncombustible. 5.3 Auto-Ignition Temperature: Not applicable. 5.4 Products of Combustion: Not pertinent. 5.5 Fire Hazards: May decompose, generating irritating chlorine gas. 5.6 Explosion Hazards: Not explosive. 5.7 Fire Fighting Media and Instructions: 5.7.1 Extinguishing Media: Water fog. Foam. Dry chemical powder. Carbon dioxide. 5.7.2 Small Fires: Use carbon dioxide, or water spray. 5.7.3 Large Fires: Use flooding quantities of water as fog. 5.8 Special Remarks on Fire Hazards: Do not use Mono Ammonium Phosphate (MAP) fire extinguishers. Such use may cause explosion with release of toxic gases. HASACHLOR Safety Data Sheet (SDS No. 102) Revision Date: 01/01/2016 (Supersedes previous revisions) Page 4 of 10 SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Small Spill: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. 6.2 Large Spill: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Never return spills in original containers for re-use. For waste disposal, see Section 13 of the SDS. 6.3 Personal Precautions, Protective Equipment & Emergency Procedures: Keep unnecessary personnel away. Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Absorb spillage to prevent material damage. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see Section 8 of the SDS. 6.4 Environmental Precautions: Do not discharge into drains, water courses or onto the ground. Environmental manager must be informed of all major releases. SECTION 7: HANDLING AND STORAGE 7.1 Handling: • Avoid contact with skin or eyes. • Do not ingest. • Avoid inhalation of vapor or mist. • Wear protective equipment if necessary. • Mix only with water in accordance with label directions. • Mixing this product with ammonia, acids, detergents, etc or with organic materials, e.g. feces, urine, etc. will release chlorine gas, which is irritating to eyes, lungs, and mucous membranes. 7.2 Hygiene Measures: • Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. • While handling this product, avoid eating, drinking or smoking. 7.3 Storage: • Do not freeze. • Store in a cool, shaded outdoor area. • Inside storage should be in a cool, dry, well-ventilated area. • To maintain hypochlorite strength, do not store in direct or heated indoor areas. • Keep in original vented container. • Keep container closed when not in use. • Do not store adjacent to chemicals that may react if spillage occurs. • If closed containers become heated, vent to release decomposition products (mainly oxygen under normal decomposition). HASACHLOR Safety Data Sheet (SDS No. 102) Revision Date: 01/01/2016 (Supersedes previous revisions) Page 5 of 10 SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Engineering Controls: Local exhaust ventilation to maintain levels below STEL (Short Term Exposure Limit) of 1 ppm as chlorine. 8.2 Personal Protection: 8.2.1 Eye / Face Protection: Wear safety glasses, goggles or face shield to prevent eye contact. 8.2.2 Skin Protection: Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin contact. Butyl rubber, Neoprene, or Nitrile Gloves should be worn when handling this material. Wear chemical resistant clothing such as a rubber apron when splashing may occur. Rinse immediately if skin is contaminated. Remove contaminated clothing promptly and wash before reuse. Clean protective equipment before reuse. 8.2.3 Respiratory Protection: Avoid breathing vapor or mist. When airborne exposure limits are exceeded (see below), use NIOSH approved respiratory protection equipment appropriate to the material and/or its components. Full facepiece equipment is recommended and, if used, replaces need for face shield and chemical goggles. For emergency and other conditions where exposure limit may be significantly exceeded, use an approved full face positive- pressure, self-contained breathing apparatus. 8.2.4 Other Safety Equipment: Eye wash facility and emergency shower should be in close proximity. 8.3 Exposure Limits: Sodium Hypochlorite Chlorine* 8.3.1 AIHA (American Industrial Hygiene Association) / WEEL (Workplace Environmental Exposure Level guides) 2010 2 mg/m3: 15 minute. (Short-term time weighted average) Not established 8.3.2 ACGIH (American Conference of Governmental Industrial Hygienists) TWA (Time Weighted Average) Not established. 0.5 ppm 8.3.3 ACGIH STEL (Short Term Exposure Limit) Not established. 1 ppm 8.3.4 OSHA PEL (Permisible Exposure Limit) Not established. 0.5 ppm 8.3.5 ACGIH Ceiling Not established. Not established 8.3.6 NIOSH (National Institute for Occupational Safety & Health) IDLH (Immediate Danger to Life & Health) Not established. 10 ppm 8.3.7 OSHA STEL (Short Term Exposure Limit) Not established. 1 ppm as Cl2 8.3.8 NIOSH (15 min. ceiling) Not established. 0.5 ppm * Chlorine is unlikely to be present as a decomposition product, but may be present in incidents of accidental mixing with other chemicals. HASACHLOR Safety Data Sheet (SDS No. 102) Revision Date: 01/01/2016 (Supersedes previous revisions) Page 6 of 10 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Appearance: Greenish yellow liquid. 9.2 Odor: Pungent. 9.3 Odor Threshold: 0.9 mg/m³. 9.4 pH: 11.2 – 11.4 (1% solution) 9.5 Melting Point: Not pertinent. 9.6 Freezing point: -23.3°C (-10°F) 9.7 Boiling Point & Boiling Range: Decomposes @ 110°C (230°F) 9.8 Flash Point: No information available. 9.9 Evaporation Rate: No information available. 9.10 Flammability (solid, gas): Not flammable. 9.11 Upper / Lower Flammability or Explosive Limits: No information available. 9.12 Vapor Pressure: 12.1 mm Hg @ 20°C (68°F) 9.13 Vapor Density: 2.61 (air=1) 9.14 Relative Density (Specific Gravity): 1.2 g/mL or 10 lb/gallon @ 20°C (68°F) 9.15 Solubility in Water: Mixes infinitely with water. 9.16 Partition Coefficient: (n-octanol / water): No information available. 9.17 Auto-ignition Temperature: No information available. 9.18 Decomposition Temperature: Decomposes @ 110°C (230°F) 9.19 Molecular Weight: 74.5 g/mole 9.20 Viscosity: 1.75 - 2.50 centipoises (varies with temperature) SECTION 10: STABILITY AND REACTIVITY 10.1 Stability: Stable under normal conditions of storage, handling, and use. 10.2 Instability / Decomposition Temperature: All bleach decomposition is dependant on temperature. For any given temperature, the higher the strength, the faster it decomposes. In summary, for every 10oC increase in storage temperature, the sodium hypochlorite will decompose at an increased rate factor of approximately 3.5. 10.3 Conditions of Instability: High heat, ultraviolet light. 10.4 Incompatibility with Various Substances: Oxidizing agents, acids, nitrogen containing organics, metals, iron, copper, nickel, cobalt, organic materials, and ammonia. 10.5 Corrosivity: Corrosive to metals. 10.6 Special Remarks on Reactivity: Rate of decomposition increases with heat. May develop chlorine if mixed with acidic solutions. 10.7 Special Remarks on Corrosivity: None. 10.8 Hazardous Polymerization: Will not occur. HASACHLOR Safety Data Sheet (SDS No. 102) Revision Date: 01/01/2016 (Supersedes previous revisions) Page 7 of 10 SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Routes of Entry: Eyes, skin, ingestion, dermal absorption. 11.2 Acute Toxicity: 11.2.1 Oral Toxicity (LD50): 3-5 g/kg (rat) 11.2.2 Dermal Toxicity (LD50): >2 g/kg (rabbit) 11.2.3 Primary Eye Irritation: Corrosive 11.2.4 Primary Skin Irritation: Corrosive 11.2.5 Inhalation Toxicity (LC50): No data available. 11.3 Chronic Effects (Human Risk Assessment): Based on the toxicity profile and exposure scenarios for sodium hypochlorite, EPA concludes that the risks from chronic and subchronic exposure to low levels of these pesticides are minimal and without consequence to human health. 11.4 Tolerance Requirement: Exempt (EPA document “Index to Pesticide Chemical Names, Part 180 Tolerance Information, and Food and Feed Commodities (by Commodity)” July 2010 SECTION 12: ECOLOGICAL INFORMATION 12.1 Ecotoxicity: Sodium hypochlorite is low in toxicity to avian wildlife, but it is highly toxic to freshwater fish and invertebrates. 12.1.1 Freshwater Fish Toxicity: Atlantic Herring (clupea harengus) LC50 = 0.033 - 0.097 mg//l/96 hr, flow through bioassay (pH: 8) Shiner Perch (cymatogaster aggregata) LC50 = 0.045 - 0.098 mg/l/96 hr, flow through bioassay (pH: 8) Three Spine Stickleback (gasterosteus aculeatus) LC50 = 0.141 - 0.193 mg/l/96 hr, flow through bioassay (pH: 8) Pink Salmon (oncorhynchus gorbuscha) LC50 = 0.023 - 0.052 mg/l/96 hr, flow through bioassay (pH: 8) Coho Salmon (oncorhynchus kisutch) LC50 = 0.026 - 0.038 mg/l/96 hr, flow through bioassay (pH: 8) English Sole (parophrys vetulus) LC50 = 0.044 - 0.144 mg/l/96 hr, flow through bioassay (pH: 8) Fat Head Minnow (pimephales promelas) LC50 = 0.22 - 0.62 mg/l/96 hr, flow through bioassay (pH: 7) 12.1.2 Invertebrate Toxicity: Water Flea (ceriodaphnia sp. 0) LC50 = 0.006 mg/l/24 hr Water Flea (daphnia magna) LC50 = 0.07 - 0.7 mg/l/24 hr Water Flea (daphnia magna) LC50 = 2.1 mg/l/96 hr Fresh Water Shrimp (gammarus fasciatus) LC50 = 0.4 mg/l/96 hr No common name (nitocra spinipes) LC50 = 0.40 mg/l/96 hr Grass Shrimp (palaemonetes pugio) LC50 = 0.52 mg/l/96 hr 12.2 Persistence: No data available. 12.3 Environmental Fate: In fresh water, sodium hypochlorite breaks down rapidly into non-toxic compounds when exposed to sunlight. In seawater, chlorine levels decline rapidly; however, hypobromite (which is acutely toxic to aquatic organisms) is formed. EPA believes that the risk of acute exposure to aquatic organisms is sufficiently mitigated by precautionary labeling and National Pollutant Discharge Elimination System (NPDES) permit requirements. 12.4 Bioconcentration: This material is not expected to bioconcentrate in organisms. 12.5 Biodegradation: This material is inorganic and not subject to biodegradation. HASACHLOR Safety Data Sheet (SDS No. 102) Revision Date: 01/01/2016 (Supersedes previous revisions) Page 8 of 10 SECTION 13: DISPOSAL CONSIDERATIONS Do not contaminate food or feed by storage, disposal, or cleaning of equipment. Product or rinsates that cannot be used should be diluted with water before disposal in a sanitary sewer. This product can be neutralized with sodium bisulfite, sodium thiosulfate, sodium sulfite. Do not confuse these products with sulfates or bisulfates. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans, or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination system (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not contaminate water containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. Dispose of in accordance with all applicable local, County, State, and Federal regulations. SECTION 14: TRANSPORT INFORMATION Inside containers (< 1.3 gallons) Container (>1.3 gallons) 14.1 UN Number Limited Quantity UN 1791 14.2 UN Proper Shipping Name -- Hypochlorite Solutions (Sodium Hypochlorite) 14.3 Transport Hazard Class -- 8 14.4 Packing Group -- PG III 14.5 Environmental Hazard (e.g. Marine Pollutant) Yes Yes 14.6 Reportable Quantity (RQ): 100 lb (45.4 kg) or 80 gallons (based on 12.5% active ingredient) 100 lb (45.4 kg) or 80 gallons (based on 12.5% active ingredient) 14.7 Materials of Trade (MOT) Exceptions. Certain hazardous materials transported in small quantities as part of a business are subject to less regulation, because of the limited hazard they pose. These materials are known as Materials of Trade. The regulations that apply to MOTs are found in 49 CFR § 173.6. This information is not intended to convey all specific regulatory or operational requirements / information relating to this product. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. HASACHLOR Safety Data Sheet (SDS No. 102) Revision Date: 01/01/2016 (Supersedes previous revisions) Page 9 of 10 SECTION 15: REGULATORY INFORMATION 15.1 U.S. Regulations: 15.1.1 OSHA HAZCOM (Hazard Communication) This material is considered hazardous under the HAZCOM Standard (29 CFR 1910.1200) 15.1.2 OSHA PSM (Process Safety Management) Not regulated under PSM Standard (29 CFR 1910.119) 15.1.3 EPA FIFRA (Federal Insecticide, Fungicide and Rodenticide Act) EPA Reg. No. :10897-26 (Registered pesticide under 40 CFR 152.10) 15.1.4 EPA TSCA (Toxic Substance Control Act) All components are listed or exempted. TSCA 12(b): This product is not subject to export notification. 15.1.5 EPA CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act) Reportable Quantity (RQ): 45.4 kg (100 lbs) or 80 gallons (based on 12.5% active ingredient). 15.1.6 EPA RMP (Risk Management Plan) Not listed. (40 CFR 68.130) 15.2 State of California Regulations: 15.2.1 Safe Drinking Water and Toxic Enforcement Act of 1986 [Proposition 65, California only]: Small quantities – less than 100 ppm (parts per million) – of impurities, including bromates, may be found in all chlorinating products, including this product. Bromates are derived from bromides, which are present in sodium chloride (table salt) from which chlorine is manufactured. Additional small quantities of bromates may be generated during the disinfection process. Bromates are known by the State of California to cause cancer when administered by the oral (drinking or ingesting) route. Read and follow label directions and use care when handling or using this product. The US Environmental Protection Agency has established a maximum contaminant level (MCL) for bromates in drinking water at 10 ppb (parts per billion). Application of this product in accordance with label directions at use dilution will not exceed this level. This warning is provided pursuant to Proposition 65, Chapter 6.6 of the California Health and Safety Code, which requires the Governor of California to publish a list of chemicals “known to the State to cause cancer or reproductive toxicity.” This list is compiled in accordance with the procedures established under the proposition, and can be obtained on the internet from California’s Office of Environmental Health Hazard Assessment at http://www.oehha.ca.gov. 15.2.2 CDPR (California Department of Pesticide Regulation) Registration No: 10897-26-ZB 15.2.3 CalARP (California Accidental Release Prevention Program) Not regulated. 15.3 Canada Regulations: 15.3.1 WHMIS (Workplace Hazardous Materials Information System) • Classification: E (Corrosive Materials) • Health Effects Criteria Met by this Chemical: E - Corrosive to skin E - TDG class 8 - corrosive substance • Ingredient Disclosure List: Included for disclosure at 1% or greater. 15.3.2 DSL (Domestic Substances List) All components of this product are on the DSL. 15.4 International Inventory: 15.4.1 AICS (Australian Inventory of Chemical Substances) On inventory or in compliance with inventory. 15.4.2 KECI (Korean Existing Chemicals Inventory) On inventory or in compliance with inventory. 15.4.3 PICCS (Philippine Inventory of Chemicals and Chemical Substances) On inventory or in compliance with inventory. 15.4.4 IECSC (Inventory of Existing Chemical Substances in China) On inventory or in compliance with inventory. 15.4.5 NZIoC (New Zealand Inventory of Chemicals) On inventory or in compliance with inventory. HASACHLOR Safety Data Sheet (SDS No. 102) Revision Date: 01/01/2016 (Supersedes previous revisions) Page 10 of 10 SECTION 16: OTHER INFORMATION 16.1 HMIS III (Hazardous Materials Identification System): 16.1.1 HEALTH 2 16.1.2 FLAMMABILITY 0 16.1.3 PHYSICAL HAZARD 1 16.1.4 PERSONAL PROTECTION See Section 8. 16.2 NFPA 704 (National Fire Protection Association): 16.2.1 HEALTH 2 16.2.2 FLAMMABILITY 0 16.2.3 INSTABILITY 0 16.2.4 SPECIAL None 16.3 International Fire Code / International Building Code: Irritant. 16.4 ANSI (American National Standards Institute): 16.4.1 Hazardous Industrial Chemicals - SDS-Preparation: Complies with ANSI Z400.1 – 2004. 16.4.2 Hazardous Industrial Chemicals - Precautionary Labeling: Complies with ANSI Z129.1 – 2006. Note: The information contained herein, while not guaranteed, was prepared by competent technical personnel and is true and accurate to the best of our knowledge and belief. NO WARRANTY OR GUARANTEE, express or implied, is made regarding the product performance, product stability, or as to any other condition of use, handling, transportation, and storage. Customer use, handling, transportation, and storage may involve additional safety and/or performance considerations. Our technical personnel will be happy to respond to questions regarding safe handling, storage, transportation, and use procedures. The safe handling, storage, transportation, and use procedures remain the sole responsibility of the customer. No suggestions for handling, storage, transportation, or use are intended as or to be construed as recommendations which may infringe on any existing patents or violate any Federal, State, and/or local law and/or regulation, ordinance, standard, etc. This Safety Data Sheet has been prepared by HASA, Inc. staff from test reports and other information available in the public domain. HASA MURIATIC ACID Safety Data Sheet (SDS No. 110) Revision Date: 09/01/2018 (Supersedes previous revisions) Page 1 of 10 HASA MURIATIC ACID Safety Data Sheet Emergency 24 Hour Telephone: CHEMTREC 800.424.9300 Corporate Headquarters: Hasa Inc. P. O. Box 802736 Santa Clarita, CA 91355 Telephone 661.259.5848 Fax 661.259.1538 SECTION 1: IDENTIFICATION 1.1 Product Identification: 1.1.1 Product Name: HASA MURIATIC ACID 1.1.2 CAS # (Chemical Abstracts Service): 7647-01-0 1.1.3 RTECS (Registry of Toxic Effects of Chemical Substances): MW4025000 1.1.4 EINECS (European Inventory of Existing Chemical Substances): 231-595-7 1.1.5 Synonym: Hydrochloric Acid, Spirits of Salt 1.1.6 Chemical Name: Hydrochloric Acid 1.1.7 Chemical Formula: HCl 1.2 Recommended Uses: Household cleaning, swimming pool water pH control and neutralization. 1.3 Company Identification: Hasa Inc. P.O. Box 802736 Santa Clarita, CA 91355 1.4 Emergency Telephone Number: CHEMTREC: 1-800-424-9300 (24 hour) 1.5 Non-Emergency Assistance: 661-259-5848 (8 AM – 5 PM PST / PDT) HASA MURIATIC ACID Safety Data Sheet (SDS No. 110) Revision Date: 09/01/2018 (Supersedes previous revisions) Page 2 of 10 SECTION 2: HAZARD(S) IDENTIFICATION Health Hazard Acute Toxicity (Oral): Category 4 Skin corrosion / irritation: Category 1 Serious eye damage / irritation Category 1 Specific Target Organ Toxicity (Single exposure) Category 3 (respiratory tract irritation) Physical Hazard Corrosive to metals. Category 1 Symbols Signal Word DANGER Hazard Statement Causes severe skin burns & eye damage. Harmful if swallowed. May cause respiratory irritation. Maybe corrosive to metals. Precautionary Statement Prevention Wear protective gloves/protective clothing/eye protection/face protection. Do not eat, drink or smoke when using this product. Do not breathe mist or vapor. Use only outdoors or in a well-ventilated area. Wash hands thoroughly after handling. Keep only in original container. Response If swallowed: Rinse mouth. Do NOT induce vomiting. If inhaled: Remove person to fresh air and keep comfortable for breathing. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Storage Store locked up. Store in a corrosive resistant container. Store in a well-ventilated place. Keep container tightly closed. Disposal Dispose of container/contents in accordance with local, regional, national, international regulations as specified. SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS Ingredient CAS No. Weight % (Approx.) 3.1 Hydrochloric Acid 7647-01-0 31.45% 3.2 Water 7732-18-5 68.55% HASA MURIATIC ACID Safety Data Sheet (SDS No. 110) Revision Date: 09/01/2018 (Supersedes previous revisions) Page 3 of 10 SECTION 4: FIRST-AID MEASURES 4.1.IF IN EYES • Hold eye open and rinse slowly and gently with water for 15-20 minutes. • Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. • Call a poison control center or doctor for treatment advice. 4.2. IF ON SKIN OR CLOTHING • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15-20 minutes. • Call a poison control center or doctor for treatment advice. 4.3.IF INHALED • Move person to fresh air. • If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. • Call a poison control center or doctor for further treatment advice. 4.4.IF SWALLOWED • Call a poison control center or doctor immediately for treatment advice. • Have person sip a glass of water if able to swallow. • Do not induce vomiting unless told to do so by a poison control center or doctor. • Do not give anything by mouth to an unconscious person. HOT LINE NUMBER Have the product container or label with you when calling a poison control center or doctor, or going for treatment. You may also contact 1-800-424-9300 for emergency medical treatment information. NOTE TO PHYSICIAN Probable mucosal damage may contraindicate the use of gastric lavage. SECTION 5: FIRE-FIGHTING MEASURES 5.1 Products of Combustion: Hydrogen and chlorine 5.2 Fire Hazards in Presence of Various Substances: Reacts with many metals to liberate hydrogen gas which can form explosive mixtures with air. 5.3 Explosion Hazards: Not sensitive. 5.4 Fire Fighting Media and Instructions: 5.4.1 Extinguishing Media: Use extinguishing measures appropriate to local circumstances and the surrounding environment. 5.4.2 Small Fires: Use carbon dioxide, dry chemical, dry sand, alcohol- resistant foam or water spray. 5.4.3 Large Fires: Water spray, fog or alcohol-resistant foam. Move containers from fire area if you can do it without risk. Use water spray or fog; do not use straight streams. Dike fire-control water for later disposal; do not scatter the material. 5.5 Fire Involving Tank Cars / Trailer Loads: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. HASA MURIATIC ACID Safety Data Sheet (SDS No. 110) Revision Date: 09/01/2018 (Supersedes previous revisions) Page 4 of 10 SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Small Spill: Gather up with a squeegee and place in pool and spa. If this is not possible, absorb with sand, diatomaceous earth or similar products and securely bag, and place in trash for collection. 6.2 Large Spill: Steps to be taken in case material is released or spilled: Spills or discharges into the environment involving large quantities of Hydrochloric Acid should be controlled and cleaned-up according to a pre-determined, affirmative written Spill Prevention and Control Program. Refer to Section 15 for spill/release reporting information. Spills should be handled immediately by neutralization and dilution of the spilled product by the use of Soda Ash (Sodium Carbonate), Lime (Calcium Hydroxide), or Limestone (Calcium Carbonate) with large amounts of water. For an interior (inside a closed space) spill be aware that the use of Soda Ash, Lime and Limestone will evolve heat and carbon dioxide and that ample ventilation must be provided. If possible without personal risk, stop leak. Try to prevent the materials from entering drains, waterways, or sewers and dispose of in accordance with local regulations. Rinse exposed area with dilute sodium carbonate solution. SECTION 7: HANDLING AND STORAGE 7.1 Handling: Keep away from skins and eyes. Do not inhale or swallow. Do not mix with chlorine type bleaches or other household chemicals. Whenever handling muriatic acid, wear protective clothing (goggles, old clothing and rubber gloves). Remove protective clothing and wash before reuse. 7.2 Storage and Disposal: Store muriatic acid in a clean, dry place in the upright position. Keep out of reach of children, pets and other animals. Rinse empty container thoroughly before discarding. HASA MURIATIC ACID Safety Data Sheet (SDS No. 110) Revision Date: 09/01/2018 (Supersedes previous revisions) Page 5 of 10 SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Engineering Controls: Local exhaust to maintain levels below Permissible Exposure Limit (PEL). 8.2 Personal Protection: When necessary, wear splash goggles or safety glasses and gloves. 8.3 Personal Protection in case of a Large Spill: Wear splash goggles or safety glasses and gloves. If natural ventilation is insufficient, wear a NIOSH approved respirator. 8.4 Exposure Guidelines: 8.4.1 ACGIH (American Conference of Governmental and Industrial Hygienists) TLV (Threshold Limit Value) 5 ppm (7 mg/m3) Ceiling 8.4.2 PEL (OSHA Permissible Exposure Limit) 5 ppm (7 mg/m3) Ceiling Limit 8.4.3 IDLH (NIOSH Immediate Danger to Life & Health) 50 ppm (75 mg/m3) 8.4.4 AIHA (American Industrial Hygiene Association) ERPG – 1 (The maximum airborne concentration below which it is believed nearly all individuals could be exposed for up to one hour without experiencing other than mild transient adverse health effects or perceiving a clearly defined objectionable odor.): 3 ppm ERPG – 2 (The maximum airborne concentration below which it is believed nearly all individuals could be exposed for up to one hour without experiencing or developing irreversible or other serious health effects or symptoms that could impair an individual’s ability to take protective action.): 20 ppm ERPG – 3 (The maximum airborne concentration below which it is believed nearly all individuals could be exposed for up to one hour without experiencing or developing life-threatening health effects.): 150 ppm HASA MURIATIC ACID Safety Data Sheet (SDS No. 110) Revision Date: 09/01/2018 (Supersedes previous revisions) Page 6 of 10 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Appearance: Colorless liquid. 9.2 Odor: Irritating and pungent odor. 9.3 Odor Threshold: 4.7 ppm @ at 25 °C 9.4 pH: <1.0 9.5 Melting Point: Not applicable. 9.6 Freezing point: -46.9°C (-52.5°F) 9.7 Boiling Point & Boiling Range: 85°C (185°F) 9.8 Flash Point: No information available. 9.9 Evaporation Rate: No information available. 9.10 Flammability (solid, gas): Nonflammable and noncombustible. 9.11 Upper / Lower Flammability or Explosive Limits: Not applicable. 9.12 Vapor Pressure: 40 mm Hg @ 30oC (86°F) 9.13 Vapor Density: No information available. 9.14 Relative Density (Specific Gravity): 1.16 @ 15.5°C (60°F) 9.15 Solubility in Water: Mixes with water in all concentrations. 9.16 Partition Coefficient: (n-octanol / water): Not applicable. 9.17 Auto-ignition Temperature: Not applicable. 9.18 Decomposition Temperature: 85oC. Rate of decomposition increases with heat. 9.19 Molecular Weight: 36.46 g/mole 9.20 Viscosity: 1.55 centipoises @ 30oC (86°F) SECTION 10: STABILITY AND REACTIVITY 10.1 Stability: Stable under normal conditions of storage, handling, and use. 10.2 Instability Temperature: 85oC. Rate of decomposition increases with heat. 10.3 Conditions of Instability: High heat, ultraviolet light. 10.4 Incompatibility with Various Substances: Oxidizing agents, acids, nitrogen containing organic, metals, iron, copper, nickel, cobalt, organic materials, and ammonia. Corrosive to most metals with evolution of hydrogen gas, which may form explosive mixtures with air. 10.5 Special Remarks on Reactivity: Rate of decomposition increases with heat. 10.6 Hazardous Polymerization: Will not occur. HASA MURIATIC ACID Safety Data Sheet (SDS No. 110) Revision Date: 09/01/2018 (Supersedes previous revisions) Page 7 of 10 SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Routes of Entry: Eyes, skin, ingestion. 11.2 Eye damage & skin corrosion: Causes eye burns. Contact with this material will cause burns to the skin, eyes and mucous membranes. Permanent eye damage including blindness could result. 11.3 Acute Oral Toxicity (LD50): NIOSH: 900 mg/kg (rabbit) 11.4 Acute Inhalation Toxicity (LC50): 3124 mg/l, 1 Hour (rat) 11.5 Toxic Effects on Humans: Harmful if swallowed. Causes digestive tract burns. Ingestion may produce burns to the lips, oral cavity, upper airway, esophagus and possibly the digestive tract. 11.6 Carcinogenic [Cancer Potential] Information: NTP (National Toxicological Program 6th Annual Report on Carcinogens): Not Listed. IARC (International Agency for Research on Cancer Monographs, V. 1-100): Not Listed. Proposition 65, California only: (Safe Drinking Water and Toxic Enforcement Act of 1986): Not Listed. 11.7 Mutagenic Effects: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. 11.8 Signs and Symptoms of Exposure: Exposure to hydrochloric acid may cause severe burns at the contact points. 11.9 Medical Conditions Generally Aggravated by Exposure: Exposure to fumes may aggravate dermatitis and breathing disorders. 11.10 Health Hazards (Acute and Chronic): Hydrogen Chloride, both as a gas and in a solution as Hydrochloric Acid, is a corrosive substance and can cause severe and painful burns on contact with any part of the body or if taken internally. The mucous membranes of the eyes and the upper respiratory tract are especially susceptible to the irritating effects of high atmospheric concentrations of Hydrogen Chloride. The gas or vapor is so penetrating and pungent that when high concentrations do occur, those exposed should immediately leave the contaminated area. HASA MURIATIC ACID Safety Data Sheet (SDS No. 110) Revision Date: 09/01/2018 (Supersedes previous revisions) Page 8 of 10 SECTION 12: ECOLOGICAL INFORMATION 12.1 Ecotoxicity General: This product is toxic to fish and aquatic organisms. Do not contaminate water containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. 12.2 Ecotoxicological Information: LC50 Shrimp 100 to 330 ppm/48 hr (salt water) LC50 Mosquito Fish 282 mg/L (24 to 96 hours) LC50 Green crabs 100 mg/L (96 hr produced no stress effects) LC50 Gold fish 180 mg/L (96 hours) Aquatic Hazard Concern Level : moderate 12.3 Persistence and Degradation: When hydrochloric acid is spilled onto soil, it will begin to infiltrate. The presence of water in the soil will influence the rate of chemical movement in the soil. During transport through the soil, hydrochloric acid will dissolve some of the soil material, in particular those of a carbonate base. The acid will be expected to remain for transport down toward the ground water table. Hydrogen chloride in water dissociates almost completely, with the hydrogen ion captured by the water molecules to form the hydronium ion. 12.4 Products of Biodegradation: Not pertinent. SECTION 13: DISPOSAL CONSIDERATIONS Do not contaminate food or feed by storage, disposal, or cleaning of equipment. Product or rinsates that cannot be used should be diluted with water before disposal in a sanitary sewer. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans, or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination system (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Dispose of in accordance with all applicable local, county, State, and Federal regulations. SECTION 14: TRANSPORT INFORMATION 14.1 Shipping Name: Hydrochloric Acid 14.2 Hazard Class / Division: 8 14.3 Identification No.: UN 1789 14.4 Packing Group: PG II 14.5 Reportable Quantity (RQ): 5,000 lb (1643 gallons) 14.6 Deposit Pails, Carboys and Drums: The shipping description for return of empty deposit pails, carboys, and drum is “RESIDUE: LAST CONTAINED UN1789, HYDROCHLORIC ACID, 8, PGII”. 14.7 Materials of Trade (MOT) Exceptions. Certain hazardous materials transported in small quantities as part of a business are subject to less regulation, because of the limited hazard they pose. These materials are known as Materials of Trade. The regulations that apply to MOTs are found in 49 CFR § 173.6. This information is not intended to convey all specific regulatory or operational requirements / information relating to this product. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. HASA MURIATIC ACID Safety Data Sheet (SDS No. 110) Revision Date: 09/01/2018 (Supersedes previous revisions) Page 9 of 10 SECTION 15: REGULATORY INFORMATION 15.1 U.S. Regulations: 15.1.1 OSHA HAZCOM (Hazard Communication) This material is considered hazardous under the HAZCOM standard (29 CFR 1910.1200). 15.1.2 OSHA PSM (Process Safety Management): Not regulated under PSM standard (29 CFR 1910.119). 15.1.3 EPA EPCRA (EPA Emergency Planning and Community Right-to-know Act): Not listed on Extremely Hazardous Substances and Their Threshold Planning Quantities. (Appendix A to 40 CFR Part 355) 15.1.4 EPA TSCA (Toxic Substance Control Act): All components are listed or exempted. TSCA 12(b): This product is not subject to export notification. 15.1.5 EPA CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act): Reportable Quantity (RQ) under CERCLA: 5000 lbs. (1643 gallons). 15.1.6 EPA FIFRA (Federal Insecticide, Fungicide, Fungicide, and Rodenticide Act): Not regulated under FIFRA standard. 15.1.7 EPA RMP (Risk Management Plan): Not regulated under RMP. (40 CFR 68.130) 15.2 State of California Regulations: 15.2.1 CDPR (California Department of Pesticide Regulation): Registration No: 10897-50008-AA (spray adjuvant) 15.2.2 CalARP (California Accidental Release Prevention): Not regulated. 15.3 Canada Regulations: 15.3.1 WHMIS (Workplace Hazardous Materials Information System): WHMIS classification: D1A - Poisonous and infectious material - Immediate and serious effects - Very toxic E - Corrosive Materials 15.3.2 DSL (Domestic Substances List): All components of this product are on the DSL. 15.4 International Inventory: 15.4.1 AICS (Australian Inventory of Chemical Substances): On inventory or in compliance with inventory. 15.4.2 KECI (Korean Existing Chemicals Inventory): On inventory or in compliance with inventory. 15.4.3 PICCS (Philippine Inventory of Chemicals and Chemical Substances): On inventory or in compliance with inventory. 15.4.4 IECSC (Inventory of Existing Chemical Substances in China): On inventory or in compliance with inventory. 15.4.5 NZIoC (New Zealand Inventory of Chemicals): On inventory or in compliance with inventory. HASA MURIATIC ACID Safety Data Sheet (SDS No. 110) Revision Date: 09/01/2018 (Supersedes previous revisions) Page 10 of 10 SECTION 16: OTHER INFORMATION 16.1 HMIS III (Hazardous Materials Identification System): 16.1.1 HEALTH 3 16.1.2 FLAMMABILITY 0 16.1.3 PHYSICAL HAZARD 0 16.1.4 PERSONAL PROTECTION See Section 8 16.2 NFPA 704 (National Fire Protection Association): 16.2.1 Health 3 16.2.2 Flammability 0 16.2.3 Instability 0 16.2.4 Special None 16.3 International Fire Code / International Building Code: Corrosive Liquid. 16.4 ANSI (American National Standards Institute): 16.4.1 Hazardous Industrial Chemicals - MSDSs-Preparation: Complies with ANSI Z400.1 – 2004. 16.4.2 Hazardous Industrial Chemicals - Precautionary Labeling: Complies with ANSI Z129.1 – 2006. Note: To convert concentrations in air (at 25°C) from ppm to mg/m3: mg/m3 = (ppm) × (molecular weight of the compound) / (24.45) For hydrochloric acid: 1 ppm = 1.49 mg/m3. Disclaimer of Liability: The information contained herein, while not guaranteed, was prepared by competent technical personnel and is true and accurate to the best of our knowledge and belief. NO WARRANTY OR GUARANTEE, express or implied, is made regarding the product performance, product stability, or as to any other condition of use, handling, transportation, and storage. Customer use, handling, transportation, and storage may involve additional safety and/or performance considerations. Our technical personnel will be happy to respond to questions regarding safe handling, storage, transportation, and use procedures. The safe handling, storage, transportation, and use procedures remain the sole responsibility of the customer. No suggestions for handling, storage, transportation, or use are intended as or to be construed as recommendations which may infringe on any existing patents or violate any Federal, State, and/or local law and/or regulation, ordinance, standard, etc. This Safety Data Sheet has been prepared by Hasa, Inc. staff from test reports and other information available in the public domain. _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ SAFETY DATA SHEET POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08 –May-2015 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufactured For and Alliance Trading, Inc. Registered By: 109 Northpark Boulevard, 4Th Floor Covington, LA 70433 Supplier Identification: Occidental Chemical Corporation 5005 LBJ Freeway P.O. Box 809050 Dallas, TX 75380-9050 1-800-752-5151 24 Hour Emergency Telephone 1-800-733-3665 or 1-972-404-3228 (USA); CHEMTREC (within USA and Number: Canada): 1-800-424-9300; CHEMTREC (outside USA and Canada): +1 703-527-3887; CHEMTREC Contract No: CCN16186 Emergency Medical: 1-800-255-3924 OxyChem® Customer Service: 1-800-752-5151 or 1-972-404-3700 Product Identifier: POOL SEASON® SUPER ALGAE DESTROYER Synonyms: Trichloroisocyanuric acid, Trichloro-s-triazinetrione, 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione,1,3,5-trichloro-, Symclosene, TCCA Product Use: Algaecide, Bactericide for pools. Uses Advised Against: None identified. This is a pesticide product, do not use it in a pesticide application that is not included on its label. 2. HAZARDS IDENTIFICATION OSHA REGULATORY STATUS: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 1 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 ********************************************************************************************************************************** EMERGENCY OVERVIEW: Color: White Physical State: Solid Appearance: Crystals, Granules Odor: Slight chlorine odor Signal Word: DANGER MAJOR HEALTH HAZARDS: CORROSIVE. CAUSES SERIOUS EYE DAMAGE. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY BE FATAL IF INHALED. HARMFUL IF SWALLOWED. PHYSICAL HAZARDS: OXIDIZING AGENT. Contact with water slowly liberates irritating and hazardous chlorine containing gases. Contamination with moisture, organic material, or other incompatible chemicals may start a reaction with generation of heat, liberation of hazardous gases, and possible fire and explosion. Contact with acids liberates toxic gas. Decomposes at temperatures above 464 °F with liberation of harmful gases. When ignited will burn with the evolution of chlorine and equally toxic gases. Do not get water inside container. Wet material may generate nitrogen trichloride, an explosion hazard. AQUATIC TOXICITY: Very toxic to aquatic organisms. Very toxic to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS: Do not get in eyes, on skin, or on clothing. Wear eye protection, face protection, protective gloves. Do not breathe dusts or mists. Use outdoors or in a well-ventilated area. Wash hands and affected skin thoroughly after handling. Do not eat, drink or smoke when using this product. Do not get water inside container, an explosion hazard. Oxidizer, keep separated from incompatible substances. ADDITIONAL HAZARD INFORMATION: This material is corrosive. Product has strong buffering capability. Use dilution. May cause burns to moist skin if not promptly removed. There is no specific antidote. ********************************************************************************************************************************** GHS CLASSIFICATION: GHS: PHYSICAL HAZARDS: Oxidizing Solid -Cat. 2 GHS: CONTACT HAZARD -SKIN: Category 1C -Causes severe skin burns and eye damage. GHS: CONTACT HAZARD -EYE: Category 1 -Causes serious eye damage GHS: ACUTE TOXICITY INHALATION: Category 2 -Fatal if inhaled GHS: ACUTE TOXICITY -ORAL: Category 4 -Harmful if swallowed. GHS: ACUTE TOXICITY DERMAL: Not acutely toxic by dermal exposure. GHS: TARGET ORGAN TOXICITY (SINGLE EXPOSURE): Category 3 -May cause respiratory tract irritation GHS: CARCINOGENICITY: This product is not classified as a carcinogen by NTP, IARC or OSHA. 2 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 GHS: HAZARDOUS TO AQUATIC ENVIRONMENT -ACUTE HAZARD: Category 1 -Very toxic to aquatic life GHS: HAZARDOUS TO AQUATIC ENVIRONMENT -CHRONIC HAZARD: Category 1 -Very toxic to aquatic life with long lasting effects UNKNOWN ACUTE TOXICITY: Not applicable. 100% of this product consists of ingredient(s) of known acute toxicity. GHS SYMBOL: Corrosion, Skull and Crossbones, Exclamation mark, Oxidizer, Environmental hazard GHS SIGNAL WORD: DANGER GHS HAZARD STATEMENTS: GHS -Physical Hazard Statement(s) May intensify fire; oxidizer GHS -Health Hazard Statement(s) Causes severe skin burns and eye damage Causes serious eye damage Fatal if inhaled Harmful if swallowed May cause respiratory irritation GHS -Environmental Hazard Statement(s) Very toxic to aquatic life Very toxic to aquatic life with long lasting effects GHS -Precautionary Statement(s) -Prevention Do not breathe dust, fume, gas, mist, vapors, or spray In case of inadequate ventilation, wear respiratory protection Wear protective gloves, protective clothing, eye, and face protection Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Keep away from heat Keep/Store away from clothing and other combustible materials Take any precaution to avoid mixing with combustibles Avoid release to the environment 3 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 GHS -Precautionary Statement(s) -Response IF INHALED: Remove person to fresh air and keep comfortable for breathing Immediately call a POISON CENTER or doctor/physician Specific treatment is urgent (see Section 4 of SDS or first aid information on this label) IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower Wash contaminated clothing before reuse IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing IF SWALLOWED: Rinse mouth. Do NOT induce vomiting IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Specific treatment (see First Aid information on product label and/or Section 4 of the SDS) In case of fire: Use large amounts of water to extinguish Collect spillage GHS -Precautionary Statement(s) -Storage Store in a well-ventilated place. Keep container tightly closed Store locked up GHS -Precautionary Statement(s) -Disposal Dispose of contents and container in accordance with applicable local, regional, national, and/or international regulations. Hazards Not Otherwise Classified (HNOC) Damp or wet material may generate nitrogen trichloride, an explosion hazard Contact with acids liberates toxic gas See Section 11: TOXICOLOGICAL INFORMATION 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms: Trichloroisocyanuric acid, Trichloro-s-triazinetrione, 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione,1,3,5-trichloro-, Symclosene, TCCA Component Percent [%] CAS Number Trichloro-s-triazinetrione 98 -100 87-90-1 Impurities 0 -2 AT15610 4. FIRST AID MEASURES INHALATION: If inhalation of dust occurs and adverse effects result, remove to unc ontaminated area. Evaluate ABC's (is Airway constricted, is Breathing occurring, and is blood Circulating) and treat symptomatically. GET MEDICAL ATTENTION IMMEDIATELY. There is no specific antidote, treat symptomatically. 4 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 SKIN CONTACT: Immediately flush contaminated areas with water. Remove contaminated clothing, jewelry and shoes. Wash contaminated areas with large amounts of water. GET MEDICAL ATTENTION IMMEDIATELY. Thoroughly clean and dry contaminated clothing before reuse. EYE CONTACT: Immediately flush contaminated eyes with a directed stream of water for as long as possible. Remove contact lenses, if present, then continue rinsing. GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: If swallowed, do not induce vomiting. Give large amounts of water. If vomiting occurs spontaneously, keep airway clear. Give more water when vomiting stops. Never give anything by mouth to an unconscious or convulsive person. GET MEDICAL ATTENTION IMMEDIATELY. Most Important Symptoms/Effects (Acute and Delayed) :. Acute Symptoms/Effects: Listed below. Inhalation (Breathing): Respiratory System Effects: Exposure to the solid product or to free chlorine evolving from the product may cause irritation, redness of upper and lower airways, coughi ng, laryngeospasm and edema, shortness of breath, bronchoconstriction, and possible pulmonary edema. The pulmonary edema may develop several hours after a severe acute exposure. Skin: Skin Corrosion. Exposure to solid along with moisture may cause redness, irritation, burning sensation, swelling, blister formation, first, second, or third degree burns. Eye: Serious Eye Damage. Exposure to eyes may cause irritation and burns to the eye lids, conjunctivitis, corneal edema, and corneal burn. Significant and prolonged contact may cause damage to the internal contents of the eye. Ingestion (Swallowing): Gastrointestinal Effects: Exposure by ingestion may cause irritation, nausea, and vomiting. May cause local tissue damage to esophagus and stomach such as burning, inflammation, local ulceration, and may cause gastrointestinal bleeding. Delayed Symptoms/Effects: -Repeated and prolonged skin contact may cause a dermatitis Interaction with Other Chemicals Which Enhance Toxicity: None known. Medical Conditions Aggravated by Exposure: May aggravate preexisting conditions such as: eye disorders that decrease tear production or have reduced integrity of the eye; skin disorders that compromise the integrity of the skin; and respiratory conditions including asthma and other breathing disorders. Protection of First-Aiders: Protect yourself by avoiding contact with this material. Use personal protective equipment. Refer to Section 8 for specific personal protective equipment recommendations. Avoid contact with skin and eyes. Do not ingest. At minimum, treating personnel should utilize PPE sufficient for prevention of bloodborne pathogen transmission. Notes to Physician: Treat as a corrosive substance. This material is more irritating to the skin and eyes in the presence of water. For prolonged exposures and significant exposures, consider delayed injury to exposed tissues. There is no antidote. Cyanuric acid is readily removed from the body via the renal system, and is not bioacc umulated. Treatment is supportive care. Follow normal parameters for airway, breathing, and circulation. 5. FIRE-FIGHTING MEASURES 5 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 Fire Hazard: Negligible fire hazard. If heated by outside source to temperatures above 240 C (464 F), this product will undergo decomposition with the evolution of noxious gases but no visible flame. Wet material may generate nitrogen trichloride, an explosion hazard. Extinguishing Media: Flood with copious amounts of water. Do not use ABC fire extinguishers. Do not use dry chemicals, carbon dioxide, or halogenated extinguishing agents. Fire Fighting: Consider evacuation of personnel located downwind. Keep unnecessary people away, isolate hazard area and deny entry. Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. Wear NIOSH approved positive -pressure self-contained breathing apparatus operated in pressure demand mode. Material which appears undamaged except for being damp on the outside, should be opened and inspected immediately. DO NOT attempt to reseal contaminated drums. Damp material should be neutralized to a non-oxidizing state. Contact OxyChem for instructions for handling and disposal of damp material. Hazardous Combustion Chlorine, Nitrogen, Nitrogen trichloride, Cyanogen chloride, Oxides of carbon, Products: Phosgene Sensitivity to Mechanical Not sensitive. Impact: Sensitivity to Static Discharge: Not sensitive. Lower Flammability Level (air): Not flammable Upper Flammability Level (air): Not flammable Flash point: Not applicable Auto-ignition Temperature: Not determined GHS: PHYSICAL HAZARDS: -Oxidizing Solid -Cat. 2 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Keep unnecessary and unprotected persons away. Isolate haza rd area and deny entry. Do not get in eyes, on skin or on clothing. Do not breathe dust, fume, gas, mist, vapors, or spray. Wear appropriate personal protective equipment recommended in Section 8, Exposure Controls / Personal Protection, of the SDS. Keep a way from combustible materials. 6 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 Methods and Materials for Containment and Cleaning Up: DO NOT add water to spilled material. DO NOT use floor sweeping compounds to clean up spills. Sweep and scoop spilled material into clean, dedicated equipment. Every attempt should be made to avoid mixing spilled material with other chemicals or debris when cleaning up. DO NOT attempt to reseal contaminated drums. DO NOT transport wet or damp material. Damp material should be neutralized to a non-oxidizing state. Contact OxyChem for instructions for handling and disposal of damp material. Environmental Precautions: This material is very toxic to aquatic life. This material is very toxic to aquatic life with long lasting effects. Keep out of water supplies and sewers. Releases should be reported, if required, to appropriate agencies. 7. HANDLING AND STORAGE Precautions for Safe Handling: Do not get in eyes, on skin, or on clothing. Avoid breathing vapors or dust when opening container. Avoid creation of dust. Wash thoroughly after handling. Wear personal protective equipment as described in Exposure Controls/Personal Protection (Section 8) of the SDS. NEVER add water to this product. Always add product to large quantities of water. Use clean, dry utensils. Do not add the product to any dispensing devic e containing residuals of other products. Keep away from heat, sparks, flame and other sources of ignition. Safe Storage Conditions: Store and handle in accordance with all current regulations and standards. (NFPA Oxidizer Class 3). Do not allow water to get in container. Store away from open flames, and combustibles. If liner is present, tie after each use. Keep container tightly closed and properly labeled. Store containers on pallets. Keep away from food, drink and animal feed. Keep separated from incompatible substances (see below or Section 10 of the Safety Data Sheet). Product has an indefinite shelf life if stored in original container in a cool, dry place. Incompatibilities/ Materials to Avoid: acids, ammonia, bases, floor sweeping compounds, calcium hypochlorite, reducing agents, organic solvents and compounds GHS: PHYSICAL HAZARDS: -Oxidizing Solid -Cat. 2 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Regulatory Exposure Limit(s): None. This product does not contain any components that have regulatory occupational exposure limits (OEL's) established. OEL: Occupational Exposure Limit; OSHA: United States Occupational Safety and Health Administration; PEL: Permissible Exposure Limit; TWA: Time Weighted Average; STEL: Short Term Exposure Limit 7 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 NON-REGULATORY EXPOSURE LIMIT(S): Listed below for the product components that have advisory (non-regulatory) occupational exposure limits (OEL's) established. -The Non-Regulatory United States Occupational Safety and Health Administration (OSHA) limits, if shown, are the Vacated 1989 PEL's (vacated by 58 FR 35338, June 30, 1993). -The American Conference of Governmental Industrial Hygienists (ACGIH) is a voluntary organization of professional industrial hygiene personnel in government or educational institut ions in the United States. The ACGIH develops and publishes recommended occupational exposure limits each year called Threshold Limit Values (TLVs) for hundreds of chemicals, physical agents, and biological exposure indices. OXY REL 0.5 mg/m3 recommended Time Weighted Average -8 hour (internal Occupational 8 hr TWA Exposure Limit) Additional Advice: Chlorine and chlorine compounds may be found in slight amounts in the head space of containers of this product. ENGINEERING CONTROLS: Use only in well-ventilated areas. Provide local exhaust ventilation where dust or mist may be generated. Ensure compliance with applicable exposure limits. PERSONAL PROTECTIVE EQUIPMENT: Eye Protection: Wear safety glasses with side-shields. Wear chemical safety goggles with a face-shield to protect against eye and skin contact when appropriate. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Skin and Body Protection: Wear protective clothing to minimize skin contact. When potential for contact with dry material exists, wear disposable coveralls suitable for dust exposure, such as Tyvek . Contaminated clothing should be removed and laundered before reuse. Hand Protection: Wear appropriate chemical resistant gloves. Consult a glove manufacturer for assistance in selecting an appropriate chemical resistant glove. Protective Material Types: Butyl rubber, Natural rubber, Neoprene, Nitrile, Polyvinyl chloride (PVC), Tyvek Respiratory Protection: A NIOSH approved respirator with N95 (dust, fume, mist) cartridges may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits, or when symptoms have been observed that are indicative of overexposure. The added protection of a full face-piece respirator is required when visible dusty conditions are encountered and eye irritation may occur. Acid gas cartridges with N95 filters are required when fumes or vapor may be generated. A respir atory protection program that meets 29 CFR 1910.134 must be followed whenever workplace conditions warrant use of a respirator. 9. PHYSICAL AND CHEMICAL PROPERTIES 8 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 Physical State: Solid Appearance: Crystals, Granules Color: White Odor: Slight chlorine odor Odor Threshold [ppm]: Not Available. Molecular Weight: 232.4 Molecular Formula: C3N303Cl3 Decomposition Temperature: 478 °F (248 °C) Boiling Point/Range: Not applicable Freezing Point/Range: Not applicable. Melting Point/Range: 478 °F (248 °C) Vapor Pressure: <0.002 Pa @ 20 °C Vapor Density (air=1): Not applicable Relative Density/Specific Gravity No data available (water=1): Density: 2.1 g/mL @ 25 °C Bulk Density: 63 -66 lbs/ft3 (loose) Water Solubility: 0.98 mg/100 g @ 20 °C pH: 2.9 -3.5 @ 25 °C (1% solution) Volatility: Not applicable Evaporation Rate (ether=1): Not applicable Partition Coefficient No data available (n-octanol/water): Flash point: Not applicable Flammability (solid, gas): Not flammable Lower Flammability Level (air): Not flammable Upper Flammability Level (air): Not flammable Auto-ignition Temperature: Not determined Viscosity: Not applicable 10. STABILITY AND REACTIVITY Reactivity: Not reactive under normal temperatures and pressures. Chemical Stability: Stable at normal temperatures and pressures. Possibility of Hazardous Reactions: Do not get water inside container. Wet material may generate nitrogen trichloride, an explosion hazard. Avoid contact with easily oxidizable organic material. Contact with acids liberates toxic gas. Conditions to Avoid: (e.g., static discharge, shock, or vibration) -. None known. Incompatibilities/ Materials to Avoid: acids. ammonia. bases. floor sweeping compounds. calcium hypochlorite. reducing agents. organic solvents and compounds. 9 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 Hazardous Decomposition Products: chlorine, nitrogen, nitrogen trichloride, cyanogen chloride, oxides of carbon, phosgene Hazardous Polymerization: Will not occur. 11.TOXICOLOGICAL INFORMATION IRRITATION DATA: PRIMARY SKIN IRRITATION: Severe Irritation, Corrosive (rabbit, 24 hr) PRIMARY EYE IRRITATION: Severe Irritation, Corrosive (rabbit, 24 hr) TOXICITY DATA: PRODUCT TOXICITY DATA: ACL 90 PLUS CHLORINATING COMPOSITION LD50 Oral: 809 mg/kg (Rat) LD50 Dermal: >2000 mg/kg (Rabbit) LC50 Inhalation: >0.09 -<0.29 mg/L (4 hr -Rat) COMPONENT TOXICITY DATA: Note: The component toxicity data is populated by the LOLI database and may differ from the product toxicity data given. Component LD50 Oral: LD50 Dermal: LC50 Inhalation: Trichloro-s-triazinetrione 87-90-1 406 mg/kg (Rat) 2000 mg/kg (Rabbit) 50 mg/L (1 hr-Rat) ********************************************************************************************************************************** POTENTIAL HEALTH EFFECTS: Eye contact: Eye exposures may cause burns to the eye lids, conjunctivitis, corneal edema, and corneal burn. Significant and prolonged contact may cause damage to the internal contents of eye. Skin contact: Exposure to solid along with moisture may cause redness, irritation, burning sensation, swelling, blister formation, first, second, or third degree burns. Dry material is less irritating than wet material. This material is not a skin sensitizer based on studies with guinea pigs. 10 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 Inhalation: This material in the form as sold is not expected to produce respiratory effects. Particles of respirable size are generally not encountered. The respirable fraction is typically less than 0.1% by weight for the granular and extra granular grades. If ground or otherwise in a powdered form, effects similar to a corrosive substance may occur. Exposure to the solid product or to free chlorine evolving from the product may cause irritation, redness of upper and lower airways, coughing, laryngeospasm and edema, shortness of breath, bronchoconstriction, and possible pulmonary edema. The pulmonary edema may develop several hours after a severe acute exposure. Ingestion: Exposure by ingestion may cause irritation, nausea, and vomiting. May cause local tissue damage to epiglottis, mucus membranes of the mouth, esophagus and stomach such as burning, inflammation, local ulceration, and may cause gastrointestinal bleeding. Chronic Effects: None identified for the parent chemical. Based on animal studies, exposure to concentrations of monosodium cyanurate at the solubility limit may cause cardiovascular, kidney and urinary bladder effects. SIGNS AND SYMPTOMS OF EXPOSURE: Listed below. Inhalation (Breathing): Respiratory System Effects: Exposure to the solid product or to free chlorine evolving from the product may cause irritation, redness of upper and lower airways, coughing, laryngeospasm and edema, shortness of breath, bronchoconstriction, and possible pulmonary edema. The pulmonary edema may develop several hours after a severe acute exposure. Skin: Skin Corrosion. Exposure to solid along with moisture may cause redness, irritation, burning sensation, swelling, blister formation, first, second, or third degree burns. Eye: Serious Eye Damage. Exposure to eyes may cause irritation and burns to the eye lids, conjunctivitis, corneal edema, and corneal burn. Significant and prolonged contact may cause damage to the internal contents of the eye. Ingestion (Swallowing): Gastrointestinal Effects: Exposure by ingestion may cause irritation, nausea, and vomiting. May cause local tissue damage to esophagus and stomach such as burning, inflammation, local ulceration, and may cause gastrointestinal bleeding. TOXICITY: Monosodium cyanurate was administered via drinking water to rats for 104 weeks at concentrations of 0, 400, 1200, 2400, and 5375 ppm (solubility limit). No compound-related effects on body weights, clinical signs of toxicity or food or water consumption were noted during the study. An increased incidence of gross lesions in the urinary tract, calculi in the kidney and lesions in the heart were observed in males receiving the highest dose level of 5375 ppm (solubility limit). The health effects seen in this study were due to precipitation of the test substance in the urinary tract when the test substance was fed at the solubility limit. Adverse health effects were not seen at lower doses where precipitation did not occur. Interaction with Other Chemicals Which Enhance Toxicity: None known. ********************************************************************************************************************************** GHS HEALTH HAZARDS: GHS: ACUTE TOXICITY -ORAL: Category 4 -Harmful if swallowed. 11 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 GHS: ACUTE TOXICITY -Not acutely toxic by dermal exposure. DERMAL: GHS: ACUTE TOXICITY -Category 2 -Fatal if inhaled. INHALATION: Skin Absorbent / Dermal Route? No. GHS: CONTACT HAZARD -Category 1C -Causes severe skin burns and eye damage SKIN: GHS: CONTACT HAZARD -EYE: Category 1 -Causes serious eye damage GHS: CARCINOGENICITY: This product is not classified as a carcinogen by NTP, IARC or OSHA. SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): Category 3 -Respiratory Tract Irritation MUTAGENIC DATA: Not classified as a mutagen per GHS criteria. Not mutagenic in 5 Salmonella strains and 1 E. coli strain with or without mammalian microsomal activation. REPRODUCTIVE TOXICITY: Not classified as a reproductive toxin per GHS criteria. There are no known or recorded effects on reproductive function or fetal development. OTHER HAZARDS: Contact with acids liberates toxic gas. 12. ECOLOGICAL INFORMATION ECOTOXICITY DATA: Fish Toxicity: LC50 Bluegill sunfish: 0.23 -0.40 mg/l (96 hr.) LC50 Rainbow trout: 0.24 -0.37 mg/l (96 hr.) Invertebrate Toxicity: LC50 Water flea: 0.17-0.80 mg/L (48 hour) Algae Toxicity: LC50 Green algae: <0.5 mg/L (3 hour) 12 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 Other Toxicity: LD50 Mallard duck (oral): 1021 -1631 mg/kg LD50 N. Bobwhite Quail (oral): 1638 mg/kg LD50 Mallard duck (diet): >10,000 ppm LD50 N. Bobwhite Quail (diet): >7422 ppm FATE AND TRANSPORT: BIODEGRADATION: This material is subject to hydrolysis Cyanuric acid produced by hydrolysis is biodegradable PERSISTENCE: This material is believed not to persist in the environment Free available chlorine is rapidly consumed by reaction with organic and inorganic materials to produce chloride ion The stable degradation products are chloride ion and cyanuric acid BIOCONCENTRATION: This material hydrolyses in water liberating free available chlorine and cyanuric aci d. These products are not bioaccumulative. ADDITIONAL ECOLOGICAL INFORMATION: This product is very toxic to fish and aquatic organisms. This product is very toxic to aquatic life with long lasting effects. Do not discharge effluent containing this pr oduct into lakes, streams, ponds, estuaries, oceans, or other waters unless in accordance with the requirements of appropriate regulatory requirements (e.g. permit and the permitting authority has been notified in writing prior to discharge). Do not discharge effluent containing this product into sewer systems without previously notifying the sewage treatment plant authority. For guidance, contact your local or regional regulatory water boards and/or other appropriate regulatory offices. 13. DISPOSAL CONSIDERATIONS Waste from material: Use or reuse if possible. This material is a registered pesticide. May be subject to disposal regulations. Dispose in accordance with all applicable regulations. Do not put product, spilled product, or filled or partially filled containers int o the trash or waste compactor. DO NOT transport wet or damp material. Damp material should be neutralized to a non-oxidizing state. Contact OxyChem for instructions for handling and disposal of damp material. Container Management: See product label for container disposal information. Dispose of container in accordance with applicable local, regional, national, and/or international regulations. Container rinsate must be disposed of in compliance with applicable regulations. 13 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 14. TRANSPORT INFORMATION LAND TRANSPORT U.S. DOT 49 CFR 172.101: Status: Regulated. For ground or air shipments only, non-bulk packages are regulated as oxidizers. Bulk Packaging or Shipment by Vessel: Regulated as follows:. UN NUMBER: UN2468 PROPER SHIPPING NAME: Trichloroisocyanuric Acid, Dry, Marine Pollutant HAZARD CLASS/ DIVISION: 5.1 PACKING GROUP: II LABELING REQUIREMENTS: 5.1, Marine Pollutant MARINE POLLUTANT: Trichloroisocyanuric Acid CANADIAN TRANSPORTATION OF D ANGEROUS GOODS: Status: Regulated. For ground or air shipments only, non-bulk packages are regulated as oxidizers. Bulk Packaging or Shipment by Vessel: Regulated as follows:. UN NUMBER: UN2468 SHIPPING NAME: Trichloroisocyanuric Acid, Dry, Marine Pollutant CLASS OR DIVISION: 5.1 PACKING/RISK GROUP: II LABELING REQUIREMENTS: 5.1, Marine Pollutant CAN. MARINE POLLUTANT: Trichloroisocyanuric Acid MARITIME TRANSPORT (IMO / IMDG) : Status -IMO / IMDG: Shipment by Vessel: Regulated UN NUMBER: UN2468 PROPER SHIPPING NAME: Trichloroisocyanuric Acid, Dry, Marine Pollutant HAZARD CLASS / DIVISION: 5.1 Packing Group: II LABELING REQUIREMENTS: 5.1, Marine Pollutant MARINE POLLUTANT: Trichloroisocyanuric Acid 14 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 15. REGULATORY INFORMATION U.S. REGULATIONS OSHA REGULATORY STATUS: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. SARA EHS Chemical (40 CFR 355.30) Not regulated EPCRA SECTIONS 311/312 HAZARD CATEGORIES (40 CFR 370.10): Fire Hazard, Reactive Hazard, Acute Health Hazard EPCRA SECTION 313 (40 CFR 372.65): Not regulated. OSHA PROCESS SAFETY (PSM) (29 CFR 1910.119): Not regulated FIFRA REGULATIONS: Registered pesticide under 40 CFR 152.10, Federal Insecticide, Fungicide and Rodenticide Act (FIFRA), EPA Reg. No. 42177-67. FIFRA LABELING REQUIREMENTS: -This chemical is a pesticide product registered by the United States Environmental Protection Agency (EPA) and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. -FIFRA Signal Word -DANGER -Corrosive -Causes irreversible eye damage and skin burns -May be fatal if swallowed -Harmful if absorbed through skin or inhaled -This pesticide is toxic to fish and aquatic organisms -Strong oxidizing agent -Contact with water slowly liberates irritating and hazardous chlorine containing g ases -Decomposes at temperatures above 437 °F with liberation of harmful gases with liberation of harmful gases -When ignited will burn with the evolution of chlorine and equally toxic gases -NEVER add water to product -Always add product to large quantities of water -Use only clean and dry utensils -DO NOT add this product to any dispensing device containing remnants of any other product -Such use may cause a violent reaction leading to fire or explosion -Contamination with moisture, organic material, or other incompatible chemicals may start a reaction with generation of heat, liberation of hazardous gases, and possible fire and explosion 15 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 NATIONAL INVENTORY STATUS U.S. INVENTORY STATUS: Toxic Substance Control Act (TSCA): All components are listed or exempt. TSCA 12(b): This product is not subject to export notification. Canadian Chemical Inventory: All components of this product are listed on either the DSL or the NDSL. STATE REGULATIONS California Proposition 65: This product and its ingredients are not listed, but it may contain impurities/trace elements known to the State of California to cause cancer or reproductive toxicity as listed under Proposition 65 State Drinking Water and Toxic Enforcement Act. For additional information, contact OxyChem Technical Services at 1-800-733-1165. Component California Proposition 65 Cancer WARNING: California Proposition 65 CRT List -Male reproductive toxin: California Proposition 65 CRT List -Female reproductive toxin: Massachusetts Right to Know Hazardous Substance List New Jersey Right to Know Hazardous Substance List New Jersey Special Health Hazards Substance List Trichloro-s-triazinetrio ne 87-90-1 Not Listed Not Listed Not Listed Listed 1892 Not Listed Component New Jersey Environmental Hazardous Substance List Pennsylvania Right to Know Hazardous Substance List Pennsylvania Right to Know Special Hazardous Substances Pennsylvania Right to Know Environmental Hazard List Rhode Island Right to Know Hazardous Substance List Trichloro-s-triazinetrione 87-90-1 Not Listed Listed Not Listed Not Listed Listed CANADIAN REGULATIONS • This product has been classified in accordance with the hazard criteria of the Controlled Pr oducts Regulations and the SDS contains all the information required by the Controlled Products Regulations WHMIS – Classifications of Substances: • Material is regulated as a pesticide, therefore is not regulated under WHMIS 16. OTHER INFORMATION Prepared by: OxyChem Corporate HESS -Product Stewardship Rev. Date: Not Revised HMIS: (SCALE 0-4) (Rated using National Paint & Coatings Association HMIS: Rating Instructions, 2nd Edition) 16 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON SUPER ALGAE DESTROYER SDS No.: R31035P SDS Revision Date: 08-May-2015 Health Rating: 3 Flammability Rating: 0 Reactivity Rating: 2 NFPA 704 -Hazard Identification Ratings (SCALE 0-4) Health Rating: 2 Flammability: 0 Reactivity Rating: 2 Reason for Revision: • Changed the SDS format to meet the GHS requirements of the revised 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200} • Updated the (M)SDS header • Product Identifier has been added or updated: SEE SECTION 1 • Updated Uses Advised Against information: SEE SECTION 1 • Revised Hazard(s) Identification information: SEE SECTIO N 2 • Emergency Overview was revised: SEE SECTION 2 • Added GHS Information: SEE SECTION 2 • Updated First Aid Measures: SEE SECTION 4 • Updated 24 Hour Emergency Telephone Number: SEE SECTION 1 • Modified Fire Fighting Measure Recommendations: SEE SECTION 5 • Revised Accidental Release Measures: SEE SECTION 6 • Revised Handling and Storage Recommendations: SEE SECTION 7 • Physical State information has been revised: SEE SECTIONS 2 and 9 • Stability and Reactivity recommendations: SEE SECTION 10 • Toxicological Information has been revised: SEE SECTION 11 • Updated Disposal Considerations. SEE SECTION 13 • Updated FIFRA Regulations: SEE SECTION 15 • Added SDS Revision Date: SEE SECTION 16 IMPORTANT: The information presented herein, while not guaranteed, was prepared by technical personnel and is true and accurate to the best of our knowledge. NO WARRANTY OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE, OR WARRANTY OR GUARANTY OF ANY OTHER KIND, EXPRESSED OR IMPLIED, IS MADE REGARDING PERFORMANCE, SAFETY, SUITABILITY, STABILITY OR OTHERWISE. This information is not intended to be all-inclusive as to the manner and conditions of use, handling, storage, disposal and other factors that may involve other or additional legal, environm ental, safety or performance considerations, and OxyChem assumes no liability whatsoever for the use of or reliance upon this information. While our technical personnel will be happy to respond to questions, safe handling and use of the product remains the responsibility of the customer. No suggestions for use are intended as, and nothing herein shall be construed as, a recommendation to infringe any existing patents or to violate any Federal, State, local or foreign laws OSHA Standard 29 CFR 1910.1200 requires that information be provided to employees regarding the hazards of chemicals by means of a hazard communication program including labeling, safety data sheets, training and access to written records. We request that you, and it is your legal duty to, make all information in this Safety Data Sheet available to your employees End of Safety Data Sheet 17 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ SAFETY DATA SHEET POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufactured For and Alliance Trading, Inc. Registered By: 109 Northpark Boulevard, 4Th Floor Covington, LA 70433 Supplier Identification: Occidental Chemical Corporation 5005 LBJ Freeway P.O. Box 809050 Dallas, TX 75380-9050 1-800-752-5151 24 Hour Emergency Telephone 1-800-733-3665 or 1-972-404-3228 (USA); CHEMTREC (within USA and Number: Canada): 1-800-424-9300; CHEMTREC (outside USA and Canada): +1 703-527 3887; CHEMTREC Contract No: CCN16186 Emergency Medical: 1-800-255-3924 OxyChem® Customer Service: 1-800-752-5151 or 1-972-404-3700 Product Identifier: POOL SEASON® CHLORINATING CONCENTRATE Synonyms: Sodium dichloroisocyanurate dihydrate, Sodium dichloro-s-triazinetrione dihydrate, 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3-dichloro-, sodium salt dihydrate, Troclosene sodium, dihydrate, SDCC dihydrate, NaDCC dihydrate, Dichloroisocyanuric acid sodium salt Product Use: Sanitizer and Algaecide for pools, spas and hot tubs. Uses Advised Against: This is a pesticide product, do not use it in a pesticide application that is not included on its label. 1 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 2. HAZARDS IDENTIFICATION OSHA REGULATORY STATUS: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). ********************************************************************************************************************************** EMERGENCY OVERVIEW: Color: White Physical State: Solid Appearance: Granules, Crystals Odor: Slight chlorine odor Signal Word: DANGER MAJOR HEALTH HAZARDS: CORROSIVE. CAUSES SERIOUS EYE DAMAGE. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY BE FATAL IF INHALED. HARMFUL IF SWALLOWED. PHYSICAL HAZARDS: OXIDIZING AGENT. Contact with water slowly liberates irritating and hazar dous chlorine containing gases. Contamination with moisture, organic material, or other incompatible chemicals may start a reaction with generation of heat, liberation of hazardous gases, and possible fire and explosion. Contact with acids liberates toxic gas. Decomposes at temperatures above 464 °F with liberation of harmful gases. When ignited will burn with the evolution of chlorine and equally toxic gases. Do not get water inside container. Wet material may generate nitrogen trichloride, an explosion hazard. AQUATIC TOXICITY: Very toxic to aquatic organisms. Very toxic to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS: Do not get in eyes, on skin, or on clothing. Wear eye protection, face protection, protective gloves. Do not breathe dusts or mists. Use outdoors or in a well-ventilated area. Wash hands and affected skin thoroughly after handling. Do not eat, drink or smoke when using this product. Do not get water inside container, an explosion hazard. Oxidizer, keep separate d from incompatible substances. ADDITIONAL HAZARD INFORMATION: This material is corrosive. Product has strong buffering capability. Use dilution. May cause burns to moist skin if not promptly removed. There is no specific antidote. ********************************************************************************************************************************** GHS CLASSIFICATION: GHS: CONTACT HAZARD -SKIN: Category 1C -Causes severe skin burns and eye damage. GHS: CONTACT HAZARD -EYE: Category 1 -Causes serious eye damage 2 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 GHS: ACUTE TOXICITY INHALATION: Category 2 -Fatal if inhaled GHS: ACUTE TOXICITY -ORAL: Category 4 -Harmful if swallowed. GHS: ACUTE TOXICITY DERMAL: Not acutely toxic by dermal exposure. GHS: TARGET ORGAN TOXICITY (SINGLE EXPOSURE): Category 3 -May cause respiratory tract irritation GHS: CARCINOGENICITY: This product is not classified as a carcinogen by NTP, IARC or OSHA. GHS: HAZARDOUS TO AQUATIC ENVIRONMENT -ACUTE HAZARD: Category 1 -Very toxic to aquatic life GHS: HAZARDOUS TO AQUATIC ENVIRONMENT -CHRONIC HAZARD: Category 1 -Very toxic to aquatic life with long lasting effects UNKNOWN ACUTE TOXICITY: Not applicable. 100% of this product consists of ingredient(s) of known acute toxicity. GHS SYMBOL: Corrosion, Skull and Crossbones, Exclamation mark, Environmental hazard GHS SIGNAL WORD: DANGER GHS HAZARD STATEMENTS: GHS -Health Hazard Statement(s) Causes severe skin burns and eye damage Causes serious eye damage Fatal if inhaled Harmful if swallowed May cause respiratory irritation GHS -Environmental Hazard Statement(s) Very toxic to aquatic life Very toxic to aquatic life with long lasting effects GHS -Precautionary Statement(s) -Prevention Do not breathe dust, fume, gas, mist, vapors, or spray In case of inadequate ventilation, wear respiratory protection Wear protective gloves, protective clothing, eye, and face protection Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Avoid release to the environment 3 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 GHS -Precautionary Statement(s) -Response IF INHALED: Remove person to fresh air and keep comfortable for breathing Immediately call a POISON CENTER or doctor/physician Specific treatment is urgent (see Section 4 of SDS or first aid information on this label) IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower Wash contaminated clothing before reuse IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing IF SWALLOWED: Rinse mouth. Do NOT induce vomiting IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Specific treatment (see First Aid information on product label and/or Section 4 of the SDS) Collect spillage GHS -Precautionary Statement(s) -Storage Store in a well-ventilated place. Keep container tightly closed Store locked up GHS -Precautionary Statement(s) -Disposal Dispose of contents and container in accordance with applicab le local, regional, national, and/or international regulations. Hazards Not Otherwise Classified (HNOC) Damp or wet material may generate nitrogen trichloride, an explosion hazard Contact with acids liberates toxic gas See Section 11: TOXICOLOGICAL INFORMATION 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms: Sodium dichloroisocyanurate dihydrate, Sodium dichloro-s-triazinetrione dihydrate, 1,3,5-Triazine 2,4,6(1H,3H,5H)-trione, 1,3-dichloro-, sodium salt dihydrate, Troclosene sodium, dihydrate, SDCC dihydrate, NaDCC dihydrate, Dichloroisocyanuric acid sodium salt Component Percent [%] CAS Number Sodium dichloroisocyanurate dihydrate 98 -100 51580-86-0 Sodium Chloride 0.1 -1 7647-14-5 4. FIRST AID MEASURES INHALATION: If inhalation of dust occurs and adverse effects result, remove to uncontaminated area. Evaluate ABC's (is Airway constricted, is Breathing occurring, and is blood Circulating) and treat symptomatically. GET MEDICAL ATTENTION IMMEDIATELY. There is no specific antidote, treat symptomatically. 4 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 SKIN CONTACT: Immediately flush contaminated areas with water. Remove contaminated clothing, jewelry and shoes. Wash contaminated areas with large amounts of water. GET MEDICAL ATTENTION IMMEDIATELY. Thoroughly clean and dry contaminated clothing before reuse. EYE CONTACT: Immediately flush contaminated eyes with a directed stream of water for as long as possible. Remove contact lenses, if present, then continue rinsing. GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: If swallowed, do not induce vomiting. Give large amounts of water. If vomiting occurs spontaneously, keep airway clear. Give more water when vomiting stops. Never give anything by mouth to an unconscious or convulsive person. GET MEDICAL ATTENTION IMMEDIATELY. Most Important Symptoms/Effects (Acute and Delayed) :. Acute Symptoms/Effects: Listed below. Inhalation (Breathing): Respiratory System Effects: Exposure to the solid product or to free chlorine evolving from the product may cause irritation, redness of upper and lower airways, coughing, laryngeospa sm and edema, shortness of breath, bronchoconstriction, and possible pulmonary edema. The pulmonary edema may develop several hours after a severe acute exposure. Skin: Skin Corrosion. Exposure to solid along with moisture may cause redness, irritati on, burning sensation, swelling, blister formation, first, second, or third degree burns. Eye: Serious Eye Damage. Exposure to eyes may cause irritation and burns to the eye lids, conjunctivitis, corneal edema, and corneal burn. Significant and prolonged contact may cause damage to the internal contents of the eye. Ingestion (Swallowing): Gastrointestinal Effects: Exposure by ingestion may cause irritation, nausea, and vomiting. May cause local tissue damage to esophagus and stomach such as burning, inflammation, local ulceration, and may cause gastrointestinal bleeding. Delayed Symptoms/Effects: -Repeated and prolonged skin contact may cause a dermatitis Interaction with Other Chemicals Which Enhance Toxicity: Contact with acids liberates toxic gas. Medical Conditions Aggravated by Exposure: May aggravate preexisting conditions such as: eye disorders that decrease tear production or have reduced integrity of the eye; skin disorders that compromise the integrity of the skin; and respiratory conditions including asthma and other breathing disorders. Protection of First-Aiders: Protect yourself by avoiding contact with this material. Use personal protective equipment. Refer to Section 8 for specific personal protective equipment recommendations. Avoid contact with skin and eyes. Do not ingest. At minimum, treating personnel should utilize PPE sufficient for prevention of bloodborne pathogen transmission. Notes to Physician: Treat as a corrosive substance. This material is more irritating to the skin and eyes in the presence of water. For prolonged exposures and significant exposures, consider delayed injury to exposed tissues. There is no antidote. Cyanuric acid is readily removed from the body via the renal system, and is not bioaccumulated. Treatment is supportive care. Follow normal parameters for airway, breathing, and circulation. 5 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 5. FIRE-FIGHTING MEASURES Fire Hazard: Negligible fire hazard. If heated by outside source to temperatures above 240 C (464 F), this product will undergo decomposition with the evolution of noxious gases but no visible flame. Wet material may generate nitrogen trichloride, an explosion hazard. Extinguishing Media: Flood with copious amounts of water. Do not use ABC fire extinguishers. Do not use dry chemicals, carbon dioxide, or halogenated extinguishing agents. Fire Fighting: Consider evacuation of personnel located downwind. Keep unnecessary people away, isolate hazard area and deny entry. Move container from fire area if it can be done without risk. Avoid inhala tion of material or combustion by-products. Stay upwind and keep out of low areas. Wear NIOSH approved positive -pressure self- contained breathing apparatus operated in pressure demand mode. Material which appears undamaged except for being damp on the outside, should be opened and inspected immediately. DO NOT attempt to reseal contaminated drums. Damp material should be neutralized to a non-oxidizing state. Contact OxyChem for instructions for handling and disposal of damp material. Hazardous Combustion Chlorine, Nitrogen, Nitrogen trichloride, Cyanogen chloride, Oxides of carbon, Products: Phosgene Sensitivity to Mechanical Not sensitive. Impact: Sensitivity to Static Discharge: Not sensitive. Lower Flammability Level (air): Not flammable Upper Flammability Level (air): Not flammable Flash point: Not applicable Auto-ignition Temperature: Not determined 6.ACCIDENTAL RELEASE MEASURES Personal Precautions: Keep unnecessary and unprotected persons away. Isolate hazard area and deny entry. Do not get in e yes, on skin or on clothing. Do not breathe dust, fume, gas, mist, vapors, or spray. Wear appropriate personal protective equipment recommended in Section 8, Exposure Controls / Personal Protection, of the SDS. 6 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 Methods and Materials for Containment and Cleaning Up: DO NOT add water to spilled material. DO NOT use floor sweeping compounds to clean up spills. Sweep and scoop spilled material into clean, dedicated equipment. Every attempt should be made to avoid mixing spilled material with other chemicals or debris when cleaning up. DO NOT attempt to reseal contaminated drums. DO NOT transport wet or damp material. Damp material should be neutralized to a non-oxidizing state. Contact OxyChem for instructions for handling and disposal of damp material. Environmental Precautions: This material is toxic to aquatic life. Keep out of water supplies and sewers. Releases should be reported, if required, to appropriate agencies. 7. HANDLING AND STORAGE Precautions for Safe Handling: Do not get in eyes, on skin, or on clothing. Avoid breathing vapors or dust when opening container. Avoid creation of dust. Wash thoroughly after handling. Wear personal protective equipment as described in Exposure Controls/Personal Protection (Section 8) of the SDS. NEVER add water to this product. Always add produc t to large quantities of water. Use clean, dry utensils. Do not add the product to any dispensing device containing residuals of other products. Safe Storage Conditions: Store and handle in accordance with all current regulations and standards. (NFPA Oxidizer Class 1). Store in original container and in a dry area where temperatures do not exceed 52 ºC (125 ºF) for 24 hours. Do not allow water to get in container. If liner is present, tie after each use. Keep container tightly closed and properly label ed. Store containers on pallets. Keep away from food, drink and animal feed. Keep separated from incompatible substances (see Section 10 of the Safety Data Sheet). Product has an indefinite shelf life if stored in original container in a cool, dry place. Incompatibilities/ Materials to Avoid: acids, ammonia, bases, floor sweeping compounds, calcium hypochlorite, reducing agents, organic solvents and compounds 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Regulatory Exposure Limit(s): None. This product does not contain any components that have regulatory occupational exposure limits (OEL's) established. OEL: Occupational Exposure Limit; OSHA: United States Occupational Safety and Health Administration; PEL: Permissible Exposure Limit; TWA: Time Weighted Average; STEL: Short Term Exposu re Limit NON-REGULATORY EXPOSURE LIMIT(S): None. This product does not contain any components that have advisory (non-regulatory) occupational exposure limits (OEL's). -The Non-Regulatory United States Occupational Safety and Health Administration (OSHA) limits, if shown, are the Vacated 1989 PEL's (vacated by 58 FR 35338, June 30, 1993). 7 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 -The American Conference of Governmental Industrial Hygienists (ACGIH) is a voluntary organization of professional industrial hygiene personnel in government or educational institutions in the United States. The ACGIH develops and publishes recommended occupational exposure limits each year called Threshold Limit Values (TLVs) for hundreds of chemicals, physical agents, and biological exposure indices. Additional Advice: Chlorine and chlorine compounds may be found in slight amounts in the head space of containers of this product. ENGINEERING CONTROLS: Use only in well-ventilated areas. Provide local exhaust ventilation where dust or mist may be generated. Ensure compliance with applicable exposure limits. PERSONAL PROTECTIVE EQUIPMENT: Eye Protection: Wear chemical safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Skin and Body Protection: Wear protective clothing to minimize skin contact. When potential for contact with dry material exists, wear disposable coveralls suitable for dust exposure, such as Tyvek . Contaminated clothing should be removed and laundered before reuse. Hand Protection: Wear appropriate chemical resistant gloves. Consult a glove manufacturer for assistance in selecting an appropriate chemical resistant glove. Protective Material Types: Butyl rubber, Natural rubber, Neoprene, Nitrile, Polyvinyl chloride (PVC), Tyvek Respiratory Protection: A NIOSH approved respirator with N95 (dust, fume, mist) cartridges may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits, or when symptoms have been observed that are indicative of overexposure. The added protection of a full face-piece respirator is required when visible dusty conditions are encountered and eye irritation may occur. Acid gas cartridges with N95 filters are required when fumes or vapor may be generated. A respiratory protection program that meets 29 CFR 1910.134 must be followed whenever workplace conditions warrant use of a respirator. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Appearance: Granules, Crystals Color: White Odor: Slight chlorine odor Odor Threshold [ppm]: Not Available. Molecular Weight: 256 Molecular Formula: C3N3O3Cl2Na.2H2O Decomposition Temperature: 486 °F (252 °C) -dehydrates at 104 -212 °F (40 -100 °C) 8 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 Boiling Point/Range: Not applicable Freezing Point/Range: Not applicable. Melting Point/Range: Decomposes without melting @ 252 °C Vapor Pressure: Not available Vapor Density (air=1): Not applicable Relative Density/Specific Gravity 1.95 g/mL @ 25 °C (water=1): Density: No data available Bulk Density: 56 -60 lbs/ft3 (loose) lbs/ft3 (loose) Water Solubility: 26.5 g/ 100 g @ 25 °C pH: 6 -7 @ 25 °C (1% solution) Volatility: Not applicable Evaporation Rate (ether=1): Not applicable Partition Coefficient (n-Kow = 0 octanol/water): Flash point: Not applicable Flammability (solid, gas): Not flammable Lower Flammability Level (air): Not flammable Upper Flammability Level (air): Not flammable Auto-ignition Temperature: Not determined Viscosity: Not applicable 10. STABILITY AND REACTIVITY Reactivity: Not reactive under normal temperatures and pressures. Chemical Stability: Stable at normal temperatures and pressures. Possibility of Hazardous Reactions: Do not get water inside container. Wet material may generate nitrogen trichloride, an explosion hazard. Avoid contact with easily oxidizable organic material. Contact with acids liberates toxic gas. Conditions to Avoid: (e.g., static discharge, shock, or vibration) -. None known. Incompatibilities/ Materials to Avoid: acids. ammonia. bases. floor sweeping compounds. calcium hypochlorite. reducing agents. organic solvents and compounds. Hazardous Decomposition Products: chlorine, nitrogen, nitrogen trichloride, cyanogen chloride, oxides of carbon, phosgene Hazardous Polymerization: Will not occur. 9 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 11.TOXICOLOGICAL INFORMATION IRRITATION DATA: PRIMARY SKIN IRRITATION: Severe Irritation, Corrosive (rabbit, 24 hr) PRIMARY EYE IRRITATION: Severe Irritation, Corrosive (rabbit, 24 hr) TOXICITY DATA: PRODUCT TOXICITY DATA: ACL 56 CHLORINATING COMPOSITION LD50 Oral: 1823 mg/kg (Rat) LD50 Dermal: >2000 mg/kg (Rabbit) LC50 Inhalation: 0.27 -1.17 mg/L (4 hr -Rat) COMPONENT TOXICITY DATA: Note: The component toxicity data is populated by the LOLI database and may differ from the product toxicity data given. Component LD50 Oral: LD50 Dermal: LC50 Inhalation: Sodium dichloroisocyanurate dihydrate 51580-86-0 735 mg/kg (Rat) 2000 mg/kg (Rabbit) 50 mg/L (1 hr-Rat) Sodium Chloride 7647-14-5 3 g/kg (Rat) 10 g/kg (Rabbit) 342 g/m (1 hr-Rat) ********************************************************************************************************************************** POTENTIAL HEALTH EFFECTS: Eye contact: Eye exposures may cause burns to the eye lids, conjunctivitis, corneal edema, and corneal burn. Significant and prolonged contact may cause damage to the internal contents of eye. Skin contact: Exposure to solid along with moisture may cause redness, irritation, burning sensation, swelling, blister formation, first, second, or third degree burns. Dry material is less irritating than wet material. This material is not a skin sensitizer based on studies with guinea pigs. Inhalation: This material in the form as sold is not expected to produce respiratory effects. Particles of respirable size are generally not encountered. The respirable fraction is typically less than 0.1% by weight for the granular and extra granular grades. If ground or otherwise in a powdered form, effects similar to a corrosive substance may occur. Exposure to the solid product or to free chlorine evolving from the product may cause irritation, redness of upper and lower airways, coughing, laryngeospasm and edema, shortness of breath, bronchoconstriction, and possible pulmonary edema. The pulmonary edema may develop several hours after a severe acute exposure. 10 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 Ingestion: Exposure by ingestion may cause irritation, nausea, and vomiting. May cause local tissue damage to epiglottis, mucus membranes of the mouth, esophagus and stomach such as burning, inflammation, local ulceration, and may cause gastrointestinal bleeding. Chronic Effects: None identified for the parent chemical. Based on animal studies, exposure to concentrations of monosodium cyanurate at the solubility limit may cause cardiovascular, kidney and urinary bladder effects. SIGNS AND SYMPTOMS OF EXPOSURE: Inhalation (Breathing): Respiratory System Effects: Exposure to the solid product or to free chlorine evolving from the product may cause irritation, redness of upper and lower airways, coughing, laryngeospasm and edema, shortness of breath, bronchoconstriction, and possible pulmonary edema. The pulmonary edema may develop several hours after a severe acute exposure. Skin: Skin Corrosion. Exposure to solid along with moisture may cause redness, irritation, burning sensation, swelling, blister formation, first, second, or third degree burns. Eye: Serious Eye Damage. Exposure to eyes may cause irritation and burns to the eye lids, conjunctivitis, corneal edema, and corneal burn. Significant and prolonged contact may cause damage to the internal contents of the eye. Ingestion (Swallowing): Gastrointestinal Effects: Exposure by ingestion may cause irritation, nau sea, and vomiting. May cause local tissue damage to esophagus and stomach such as burning, inflammation, local ulceration, and may cause gastrointestinal bleeding. TOXICITY: Monosodium cyanurate was administered via drinking water to rats for 104 wee ks at concentrations of 0, 400, 1200, 2400, and 5375 ppm (solubility limit). No compound-related effects on body weights, clinical signs of toxicity or food or water consumption were noted during the study. An increased incidence of gross lesions in the ur inary tract, calculi in the kidney and lesions in the heart were observed in males receiving the highest dose level of 5375 ppm (solubility limit). The health effects seen in this study were due to precipitation of the test substance in the urinary tract w hen the test substance was fed at the solubility limit. Adverse health effects were not seen at lower doses where precipitation did not occur. Interaction with Other Chemicals Which Enhance Toxicity: Contact with acids liberates toxic gas. ********************************************************************************************************************************** GHS HEALTH HAZARDS: GHS: ACUTE TOXICITY -ORAL: Category 4 -Harmful if swallowed. GHS: ACUTE TOXICITY -Not acutely toxic by dermal exposure. DERMAL: GHS: ACUTE TOXICITY -Category 2 -Fatal if inhaled. INHALATION: GHS: CONTACT HAZARD -Category 1C -Causes severe skin burns and eye damage SKIN: GHS: CONTACT HAZARD -EYE: Category 1 -Causes serious eye damage 11 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 GHS: CARCINOGENICITY: This product is not classified as a carcinogen by NTP, IARC or OSHA. SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): Category 3 -Respiratory Tract Irritation MUTAGENIC DATA: Not classified as a mutagen per GHS criteria. Not mutagenic in 5 Salmonella strains and 1 E. coli strain with or without mammalian microsomal activation. REPRODUCTIVE TOXICITY: Not classified as a reproductive toxin per GHS criteria. There are no known or recorded effects on reproductive function or fetal development. OTHER HAZARDS: Contact with acids liberates toxic gas. 12. ECOLOGICAL INFORMATION ECOTOXICITY DATA: Fish Toxicity: LC50 Bluegill sunfish: 0.25-1.0 mg/L (96 hour) LC50 Rainbow trout: 0.13-0.36 mg/L (96 hour) LC50 Inland silversides: 1.21 mg/L (96 hour) Invertebrate Toxicity: LC50 Water flea: 0.196 mg/L (48 hour) LC50 Mysid shrimp: 1.65 mg/L (96 hour) Other Toxicity: LD50 Mallard duck (oral): 1,916 mg/kg LD50 N. Bobwhite Quail (oral): 1,732 mg/kg LD50 Mallard duck (diet): >10,000 ppm LD50 N. Bobwhite Quail (diet): >10,000 ppm FATE AND TRANSPORT: BIODEGRADATION: This material is subject to hydrolysis Cyanuric acid produced by hydrolysis is biodegradable PERSISTENCE: This material is believed not to persist in the environment Free available chlorine is rapidly consumed by reaction with organic and inorganic materials to produce chloride ion The stable degradation products are chloride ion and cyanuric acid BIOCONCENTRATION: This material hydrolyses in water liberating free available chlorine and cyanuric acid. These products are not bioaccumulative. 12 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 ADDITIONAL ECOLOGICAL INFORMATION: This product is very toxic to fish and aquatic organisms. This product is very toxic to aquatic life with long lasting ef fects. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans, or other waters unless in accordance with the requirements of appropriate regulatory requirements (e.g. permit and the permitting authority has been not ified in writing prior to discharge). Do not discharge effluent containing this product into sewer systems without previously notifying the sewage treatment plant authority. For guidance, contact your local or regional regulatory water boards and/or other appropriate regulatory offices. 13. DISPOSAL CONSIDERATIONS Waste from material: Use or reuse if possible. This material is a registered pesticide. May be subject to disposal regulations. Dispose in accordance with all applicable regulations. Do not put product, spilled product, or filled or partially filled containers into the trash or waste compactor. DO NOT transport wet or damp material. Damp material should be neutralized to a non-oxidizing state. Contact OxyChem for instructions for handling and disposal of damp material. Container Management: See product label for container disposal information. Dispose of container in accordance with applicable local, regional, national, and/or international regulations. Container rinsate must be disposed of in compliance with applicable regulations. 14. TRANSPORT INFORMATION LAND TRANSPORT U.S. DOT 49 CFR 172.101: Status: Non-Bulk Packaging: Not Regulated unless transported by vessel. Bulk Packaging or Shipment by Vessel: Regulated as follows:. UN NUMBER: UN3077 PROPER SHIPPING NAME: Environmentally Hazardous Substance, Solid, n.o.s. (Sodium dichloroisocyanurate dihydrate), Marine Pollutant HAZARD CLASS/ DIVISION: 9 PACKING GROUP: III LABELING REQUIREMENTS: 9, Marine Pollutant MARINE POLLUTANT: Sodium dichloroisocyanurate dihydrate CANADIAN TRANSPORTATION OF DANGEROUS GOODS: 13 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 Status: Non-Bulk Packaging: Not Regulated unless transported by vessel. Bulk Packaging or Shipment by Vessel: Regulated as follows:. UN NUMBER: UN3077 SHIPPING NAME: Environmentally Hazardous Substance, Solid, n.o.s. (Sodium dichloroisocyanurate dihydrate), Marine Pollutant CLASS OR DIVISION: 9 PACKING/RISK GROUP: III LABELING REQUIREMENTS: 9, Marine Pollutant CAN. MARINE POLLUTANT: Sodium dichloroisocyanurate dihydrate MARITIME TRANSPORT (IMO / IMDG) : Status -IMO / IMDG: Shipment by Vessel: Regulated UN NUMBER: UN3077 PROPER SHIPPING NAME: Environmentally Hazardous Substance, Solid, n.o.s. (Sodium dichloroisocyanurate dihydrate), Marine Pollutant HAZARD CLASS / DIVISION: 9 Packing Group: III LABELING REQUIREMENTS: 9, Marine Pollutant MARINE POLLUTANT: Sodium dichloroisocyanurate dihydrate 15. REGULATORY INFORMATION U.S. REGULATIONS OSHA REGULATORY STATUS: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. SARA EHS Chemical (40 CFR 355.30) Not regulated EPCRA SECTIONS 311/312 HAZARD CATEGORIES (40 CFR 370.10): Fire Hazard, Reactive Hazard, Acute Health Hazard EPCRA SECTION 313 (40 CFR 372.65): Not regulated. 14 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 OSHA PROCESS SAFETY (PSM) (29 CFR 1910.119): Not regulated FIFRA REGULATIONS: Registered pesticide under 40 CFR 152.10, Federal Insecticide, Fungicide and Rodenticide Act (FIFRA), EPA Reg. No. 42177-80 FIFRA LABELING REQUIREMENTS: -This chemical is a pesticide product registered by the United States Environmental Protection Agency (EPA) and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. -FIFRA Signal Word -DANGER -Corrosive -Causes irreversible eye damage -May be fatal if inhaled -Harmful if swallowed or absorbed through skin -This pesticide is toxic to fish and aquatic organisms -Strong oxidizing agent -Contact with water slowly liberates irritating and hazardous chlorine containing gases -Decomposes at temperatures above 464 °F with liberation of harmful gases -When ignited will burn with the evolution of chlorine and equally toxic gases -NEVER add water to product -Always add product to large quantities of water -Use only clean and dry utensils -DO NOT add this product to any dispensing device containing remnants of any other product -Such use may cause a violent reaction leading to fire or explosion -Contamination with moisture, organic material, or other incompatible chemicals may start a reaction with generation of heat, liberation of hazardous gases, and possible fire and explosion NATIONAL INVENTORY STATUS U.S. INVENTORY STATUS: Toxic Substance Control Act (TSCA): All components are listed or exempt. TSCA 12(b): This product is not subject to export notification. Canadian Chemical Inventory: All components of this product are listed on either the DSL or the NDSL. STATE REGULATIONS California Proposition 65: This product and its ingredients are not listed, but it may contain impurities/trace elem ents known to the State of California to cause cancer or reproductive toxicity as listed under Proposition 65 State Drinking Water and Toxic Enforcement Act. For additional information, contact OxyChem Technical Services at 1-800-733-1165. 15 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 Component California Proposition 65 Cancer WARNING: California Proposition 65 CRT List -Male reproductive toxin: California Proposition 65 CRT List -Female reproductive toxin: Massachusetts Right to Know Hazardous Substance List New Jersey Right to Know Hazardous Substance List New Jersey Special Health Hazards Substance List Sodium dichloroisocyanurate dihydrate 51580-86-0 Not Listed Not Listed Not Listed Listed 1694 Not Listed Component New Jersey Environmental Hazardous Substance List Pennsylvania Right to Know Hazardous Substance List Pennsylvania Right to Know Special Hazardous Substances Pennsylvania Right to Know Environmental Hazard List Rhode Island Right to Know Hazardous Substance List Sodium dichloroisocyanurate dihydrate 51580-86-0 Not Listed Listed Not Listed Not Listed Listed CANADIAN REGULATIONS • This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required b y the Controlled Products Regulations WHMIS -Classifications of Substances: • Material is regulated as a pesticide, therefore is not regulated under WHMIS 16. OTHER INFORMATION Prepared by: OxyChem Corporate HESS -Product Stewardship Rev. Date: Not Revised HMIS: (SCALE 0-4) (Rated using National Paint & Coatings Association HMIS: Rating Instructions, 2nd Edition) Health Rating: 3 Flammability Rating: 0 Reactivity Rating: 1 NFPA 704 -Hazard Identification Ratings (SCALE 0-4) Health Rating: 2 Flammability: 0 Reactivity Rating: 1 16 of 17 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ POOL SEASON CHLORINATING CONCENTRATE SDS No.: R31033P SDS Revision Date: 07-May-2015 Reason for Revision: • Changed the SDS format to meet the GHS requirements of the revised 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200} • Updated the (M)SDS header • Product Identifier has been added or updated: SEE SECTION 1 • Updated Uses Advised Against information: SEE SECTION 1 • Revised Hazard(s) Identification information: SEE SECTION 2 • Emergency Overview was revised: SEE SECTION 2 • Added GHS Information: SEE SECTION 2 • Updated First Aid Measures: SEE SECTION 4 • Updated 24 Hour Emergency Telephone Number: SEE SECTION 1 • Modified Fire Fighting Measure Recommendations: SEE SECTION 5 • Revised Accidental Release Measures: SEE SECTION 6 • Revised Handling and Storage Recommendations: SEE SECTION 7 • Physical State information has been revised: SEE SECTIONS 2 and 9 • Stability and Reactivity recommendations: SEE SECTION 10 • Toxicological Information has been revised: SEE SECTION 11 • Updated Disposal Considerations. SEE SECTION 13 • Updated FIFRA Regulations: SEE SECTION 15 • Added SDS Revision Date: SEE SECTION 16 IMPORTANT: The information presented herein, while not guaranteed, was prepared by technical personnel and is true and accurate to the best of our knowledge. NO WARRANTY OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE, OR WARRANTY OR GUARANTY OF ANY OTHER KIND, EXPRESSED OR IMPLIED, IS MADE REGARDING PERFORMANCE, SAFETY, SUITABILITY, STABILITY OR OTHERWISE. This information is not intended to be all-inclusive as to the manner and conditions of use, handling, storage, disposal and other factors that may involve other or additional legal, environmental, safety or performance considerations, and OxyChem assumes no liability whatsoever for the use of or reliance upon this information. While our technical personnel will be happy to respond to questions, safe handling and use of the product remains the responsibility of the customer. No suggestions for use are intended as, and nothing herein shall be construed as, a recommendation to infringe any existing patents or to violate any Federal, State, local or foreign laws OSHA Standard 29 CFR 1910.1200 requires that information be provided to employees regarding the hazards of chemicals by means of a hazard communication program including labeling, safety data sheets, training and access to written records. We request that you, and it is your legal duty to, make all information in this Safety Data Sheet available to your employees End of Safety Data Sheet 17 of 17 City of La Quinta Riverside County Fire Department Office of the Fire Marshal 78495 Calle Tampico, La Quinta, CA 92253 Phone 760-777-7158 FIRE DEPARTMENT OPERATIONAL PERMIT: Hazardous Materials Storage and Use ISSUED DATE: 9/29/2021 ISSUED TIME: 12:00 pm PERMIT NUMBER: FM2021-0003 ORGANIZATION NAME: DISCOUNT POOL & SPA SUPPLY OCCUPANCY CLASS.: M - MERCANTILE LOCATION ADDRESS: 50855 WASHINGTON ST #2B CONTACT PERSON(S): MARCOS PERALES PHONE NUMBER: 760-574-3530 Based on the current edition of the California Fire Code Chapter 50, it has been determined that the following type of hazards may be stored or used within the establishment. TYPE OF HAZARD REPORTED QUANTITY *Not to exceed MAQs STORAGE USE-CLOSED USE OPEN CORROSIVES 1974# / 108 GAL 0 0 HIGHLY TOXICS 0 0 0 TOXIC 1974# / 108 GAL 0 0 -------- ----------- ----------- ----------- -------- ----------- ----------- ----------- -------- ----------- ----------- ----------- This permit of clearance by the local authority having jurisdiction is being presented to the above stated organization for their compliance with local and state requirements to store and utilize in the quantities identified . This permit is to be prominently displayed at the business along with the other required permits and licensing. This permit is valid for only this specific addressed location and the listed pieces of equipment in the approved submittal. Failure to comply with the City of La Quinta Municipal Code requirements along with the applicable codes standards and local Fire Department Technical Policies will result in the immediate revocation of this permit. Office of the Fire Marshal Representative: Print: Sign: Date: